3-乙炔基-1-(苯磺酰基)-1H-吲哚合成路线 （共 9 条）
反应条件
n-butyllithium in tetrahydrofuran; hexane
T=-78 - 20°C;
参考文献
Roy, Sudipta; Gribble, Gordon W.
Synthetic Communications, 2007 , vol. 37, # 5 p. 829 - 837
反应条件
1: I2; KOH
2: NaH
3: CuI; Et3N / Pd(PPh3)4
4: K2CO3 / methanol
View Scheme
参考文献
Tanaka, Katsunori; Kobayashi, Toyoharu; Mori, Hajime; Katsumura, Shigeo
Journal of Organic Chemistry, 2004 , vol. 69, # 18 p. 5906 - 5925
反应条件
1: NaH
2: CuI; Et3N / Pd(PPh3)4
3: K2CO3 / methanol
View Scheme
参考文献
Tanaka, Katsunori; Kobayashi, Toyoharu; Mori, Hajime; Katsumura, Shigeo
Journal of Organic Chemistry, 2004 , vol. 69, # 18 p. 5906 - 5925
反应条件
1: CuI; Et3N / Pd(PPh3)4
2: K2CO3 / methanol
View Scheme
参考文献
Tanaka, Katsunori; Kobayashi, Toyoharu; Mori, Hajime; Katsumura, Shigeo
Journal of Organic Chemistry, 2004 , vol. 69, # 18 p. 5906 - 5925
反应条件
sec.-butyllithium in tetrahydrofuran; cyclohexane
T=-78°C; 0.25 h;
参考文献
Roy, Sudipta; Gribble, Gordon W.
Synthetic Communications, 2007 , vol. 37, # 5 p. 829 - 837
反应条件
potassium carbonate in methanol
参考文献
Tanaka, Katsunori; Kobayashi, Toyoharu; Mori, Hajime; Katsumura, Shigeo
Journal of Organic Chemistry, 2004 , vol. 69, # 18 p. 5906 - 5925
反应条件
1: 96 percent / NaOH; tetra-n-butylammonium hydrogen sulfate / CH2Cl2 / 3 h / 0 - 20 °C
2: 97 percent / triphenylphosphine / CH2Cl2 / 5 h / 0 °C
3: 37 percent / n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
参考文献
Roy, Sudipta; Gribble, Gordon W.
Synthetic Communications, 2007 , vol. 37, # 5 p. 829 - 837
反应条件
1: 97 percent / triphenylphosphine / CH2Cl2 / 5 h / 0 °C
2: 37 percent / n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
参考文献
Roy, Sudipta; Gribble, Gordon W.
Synthetic Communications, 2007 , vol. 37, # 5 p. 829 - 837
反应条件
1: 96 percent / NaOH; tetra-n-butylammonium hydrogen sulfate / CH2Cl2 / 3 h / 0 - 20 °C
2: 97 percent / triphenylphosphine / CH2Cl2 / 5 h / 0 °C
3: 37 percent / n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
参考文献
Roy, Sudipta; Gribble, Gordon W.
Synthetic Communications, 2007 , vol. 37, # 5 p. 829 - 837
