(eta1-烯丙基)二羰基(eta5-环戊二烯基)铁合成路线 （共 16 条）
反应条件
in acetonitrile Kinetics; Under Ar, CCl4 is added to soln. of (C5H5)Fe(CO)2(CH2CHCH2), reaction is completed in 1-2 days at 25°C, further products.; Monitored by UV, analyzed by gas chromy.;
参考文献
Organometallics, , vol. 7, p. 2146 - 2149
反应条件
in acetonitrile Kinetics; Under Ar, CCl4 is added to soln. of (C5H5)Fe(CO)2(CH2CHCH2), reaction is completed in 1-2 days at 25°C, further products.; Monitored by UV, analyzed by gas chromy.;
参考文献
Organometallics, , vol. 7, p. 2146 - 2149
反应条件
in acetonitrile Kinetics; Under Ar, CCl4 is added to soln. of (C5H5)Fe(CO)2(CH2CHCH2), reaction is completed in 1-2 days at 25°C, further products.; Monitored by UV, analyzed by gas chromy.;
参考文献
Organometallics, , vol. 7, p. 2146 - 2149
反应条件
HCl; SO2 in sulfur dioxide
N2-atmosphere; passing HCl through Fe-complex soln. (-78°C), treatment with NH4PF6; evapn., washing (CH2Cl2, CHCl3/Me2CO=10:1), dissoln. in SO2 (-78°C), filtration, evapn.; elem. anal.;
参考文献
Chen, L. S.; Su, S. R.; Wojcicki, A.
Inorganica Chimica Acta, 1978 , vol. 27, p. 79 - 90
反应条件
in acetonitrile
Kinetics; Under Ar, CCl4 is added to soln. of (C5H5)Fe(CO)2(CH2CHCH2), reaction is completed in 1-2 days at 25°C, further products.; Monitored by UV, analyzed by gas chromy.;
参考文献
Lee, Mei-Tsu; Watermann, Paul S.; Magnuson, Roy H.; Meirowitz, Randy E.; Prock, Alfred; Giering, Warren B.
Organometallics, 1988 , vol. 7, p. 2146 - 2149
反应条件
KI; SO2 in sulfur dioxide
N2-atmosphere; condensation of SO2 onto Fe-complex (-78°C), addn.of excess KI, warming to -10°C (after 15 min), stirring (2 h); evapn., extn. into CHCl3, filtration, evapn. (reduced pressure), chromy.(Al2O3);
参考文献
Chen, L. S.; Su, S. R.; Wojcicki, A.
Inorganica Chimica Acta, 1978 , vol. 27, p. 79 - 90
反应条件
in acetonitrile
Kinetics; Under Ar, CCl4 is added to soln. of (C5H5)Fe(CO)2(CH2CHCH2), reaction is completed in 1-2 days at 25°C, further products.; Monitored by UV, analyzed by gas chromy.;
参考文献
Lee, Mei-Tsu; Watermann, Paul S.; Magnuson, Roy H.; Meirowitz, Randy E.; Prock, Alfred; Giering, Warren B.
Organometallics, 1988 , vol. 7, p. 2146 - 2149
反应条件
SO2 in sulfur dioxide
N2-atmosphere; refluxing (0.5 h); evapn., chromy. (Al2O3, C6H6, then CHCl3; or Florisil, CHCl3/Me2CO); elem. anal.;
参考文献
Downs, R. L.; Wojcicki, A.
Inorganica Chimica Acta, 1978 , vol. 27, p. 91 - 104
反应条件
SO2 in sulfur dioxide
N2-atmosphere; condensation of SO2 onto Fe-complex (-20 to -10°C), immediate evapn. at -10 to 0°C (during 10 min);
参考文献
Chen, L. S.; Su, S. R.; Wojcicki, A.
Inorganica Chimica Acta, 1978 , vol. 27, p. 79 - 90
反应条件
SO2 in sulfur dioxide
N2-atmosphere; refluxing (0.5 h); evapn., chromy. (Al2O3, C6H6, then CHCl3; or Florisil, CHCl3/Me2CO); elem. anal.;
参考文献
Downs, R. L.; Wojcicki, A.
Inorganica Chimica Acta, 1978 , vol. 27, p. 91 - 104
