1-(3-烯丙基-2,4-二羟基苯基)乙酮合成路线 （共 11 条）
反应条件
in xylene T=215°C; 18 h;
参考文献
Manchand; Micheli; Saposnik
Tetrahedron, 1992 , vol. 48, # 43 p. 9391 - 9398
反应条件
1: 56 percent / K2CO3 / acetone / Heating 2: Heating View Scheme
参考文献
Manchand; Micheli; Saposnik
Tetrahedron, 1992 , vol. 48, # 43 p. 9391 - 9398
反应条件
Claisen rearrangement; Heating;
参考文献
Gozzo, Fabio Cesar; Fernandes, Sergio Antonio; Rodrigues, Denise Cristina; Eberlin, Marcos Nogueira; Marsaioli, Anita Jocelyne
Journal of Organic Chemistry, 2003 , vol. 68, # 14 p. 5493 - 5499
反应条件
hydrogen; platinum on activated charcoal in tetrahydrofuran; toluene P=1551.4 Torr; Ambient temperature;
参考文献
Manchand; Micheli; Saposnik
Tetrahedron, 1992 , vol. 48, # 43 p. 9391 - 9398
参考文献
MERCK FROSST CANADA INC.
Patent: EP244164 A1, 1987 ;
反应条件
1.1: OsO4; KIO4 / ethyl acetate; H2O 1.2: 230 mg / H3PO4 / 0.33 h / Heating 2.1: 70 mg / KOH / ethanol / 75 h / 20 °C 3.1: 0.51 g / 30 percent aq. H2O2; aq. NaOH; pyridine / 60 - 70 °C 4.1: 0.68 g / K2CO3 / acetone / 2 h / Heating View Scheme
参考文献
Hossain, M. Amzad; Das; Salehuddin
Pakistan Journal of Scientific and Industrial Research, 2003 , vol. 46, # 1 p. 31 - 32
反应条件
1.1: OsO4; KIO4 / ethyl acetate; H2O 1.2: 230 mg / H3PO4 / 0.33 h / Heating 2.1: 70 mg / KOH / ethanol / 75 h / 20 °C View Scheme
参考文献
Hossain, M. Amzad; Das; Salehuddin
Pakistan Journal of Scientific and Industrial Research, 2003 , vol. 46, # 1 p. 31 - 32
反应条件
1: With osmium(VIII) oxide; potassium meta-periodate in water; ethyl acetate
2: With phosphoric acid
0.333333 h; Heating;
参考文献
Hossain, M. Amzad; Das; Salehuddin
Pakistan Journal of Scientific and Industrial Research, 2003 , vol. 46, # 1 p. 31 - 32
反应条件
1: 96 percent / H2 / 5 percent Pt/C / toluene; tetrahydrofuran / 1551.4 Torr / Ambient temperature
2: 81 percent / K2CO3, tris(3,6-dioxa-heptyl)amine / toluene / 6 h / Heating
3: 99 percent / aq. NaOH / methanol / 1.25 h / Heating
4: 2 N HCl
View Scheme
参考文献
Manchand; Micheli; Saposnik
Tetrahedron, 1992 , vol. 48, # 43 p. 9391 - 9398
反应条件
potassium carbonate; potassium iodide in acetone
Heating;
参考文献
Appleton,R.A. et al.
Journal of Medicinal Chemistry, 1977 , vol. 20, p. 371 - 379
