6-甲氧基-2-乙酰萘合成路线 （共 124 条）
反应条件
1: 1) 10 M BH3*SMe2, 2) 10percent aq. NaOH, 30percent aq. H2O2 / 1) THF, 0 deg C, 1 h, 2) rt, 6 h 2: 94 percent / oxalyl chloride, DMSO, NEt3 / CH2Cl2 / -78 °C 3: 35 percent / KMnO4, MgSO4 / acetone / 2 h View Scheme
参考文献
Shishido, Kozo; Yamashita, Akitake; Hiroya, Kou; Fukumoto, Keiichiro
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 469 - 475
反应条件
1: 53 percent / DDQ / benzene / 4.7 h / Heating 2: 1) 10 M BH3*SMe2, 2) 10percent aq. NaOH, 30percent aq. H2O2 / 1) THF, 0 deg C, 1 h, 2) rt, 6 h 3: 94 percent / oxalyl chloride, DMSO, NEt3 / CH2Cl2 / -78 °C 4: 35 percent / KMnO4, MgSO4 / acetone / 2 h View Scheme
参考文献
Shishido, Kozo; Yamashita, Akitake; Hiroya, Kou; Fukumoto, Keiichiro
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 469 - 475
反应条件
1: 87 percent / MnO2 / various solvent(s) / 36 h / 180 °C 2: 53 percent / DDQ / benzene / 4.7 h / Heating 3: 1) 10 M BH3*SMe2, 2) 10percent aq. NaOH, 30percent aq. H2O2 / 1) THF, 0 deg C, 1 h, 2) rt, 6 h 4: 94 percent / oxalyl chloride, DMSO, NEt3 / CH2Cl2 / -78 °C 5: 35 percent / KMnO4, MgSO4 / acetone / 2 h View Scheme
参考文献
Shishido, Kozo; Yamashita, Akitake; Hiroya, Kou; Fukumoto, Keiichiro
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 469 - 475
反应条件
1: 1) Mg / 1) diethyl ether, 2) rt, 2 h 2: BF3*Et2O / CH2Cl2 / 0.5 h / -78 °C 3: 87 percent / MnO2 / various solvent(s) / 36 h / 180 °C 4: 53 percent / DDQ / benzene / 4.7 h / Heating 5: 1) 10 M BH3*SMe2, 2) 10percent aq. NaOH, 30percent aq. H2O2 / 1) THF, 0 deg C, 1 h, 2) rt, 6 h 6: 94 percent / oxalyl chloride, DMSO, NEt3 / CH2Cl2 / -78 °C 7: 35 percent / KMnO4, MgSO4 / acetone / 2 h View Scheme
参考文献
Shishido, Kozo; Yamashita, Akitake; Hiroya, Kou; Fukumoto, Keiichiro
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 469 - 475
反应条件
1: 91 percent / Et3SiH, CF3CO2H / CH2Cl2 / Ambient temperature 2: 94 percent / oxalyl chloride, DMSO, NEt3 / CH2Cl2 / -78 °C 3: 35 percent / KMnO4, MgSO4 / acetone / 2 h View Scheme
参考文献
Shishido, Kozo; Yamashita, Akitake; Hiroya, Kou; Fukumoto, Keiichiro
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 469 - 475
反应条件
1: 77 percent / MnO2 / various solvent(s) / 120 h / 180 °C 2: 1) 10 M BH3*SMe2, 2) 10percent aq. NaOH, 30percent aq. H2O2 / 1) THF, 0 deg C, 1 h, 2) rt, 6 h 3: 94 percent / oxalyl chloride, DMSO, NEt3 / CH2Cl2 / -78 °C 4: 35 percent / KMnO4, MgSO4 / acetone / 2 h View Scheme
参考文献
Shishido, Kozo; Yamashita, Akitake; Hiroya, Kou; Fukumoto, Keiichiro
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 469 - 475
反应条件
1: 75 percent / 5percent aq. HCl / tetrahydrofuran / 19 h / Ambient temperature 2: 91 percent / Et3SiH, CF3CO2H / CH2Cl2 / Ambient temperature 3: 94 percent / oxalyl chloride, DMSO, NEt3 / CH2Cl2 / -78 °C 4: 35 percent / KMnO4, MgSO4 / acetone / 2 h View Scheme
参考文献
Shishido, Kozo; Yamashita, Akitake; Hiroya, Kou; Fukumoto, Keiichiro
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 469 - 475
反应条件
1: 1) Mg / 1) diethyl ether, 2) rt, 2 h 2: BF3*Et2O / CH2Cl2 / 0.5 h / -78 °C 3: 77 percent / MnO2 / various solvent(s) / 120 h / 180 °C 4: 1) 10 M BH3*SMe2, 2) 10percent aq. NaOH, 30percent aq. H2O2 / 1) THF, 0 deg C, 1 h, 2) rt, 6 h 5: 94 percent / oxalyl chloride, DMSO, NEt3 / CH2Cl2 / -78 °C 6: 35 percent / KMnO4, MgSO4 / acetone / 2 h View Scheme
参考文献
Shishido, Kozo; Yamashita, Akitake; Hiroya, Kou; Fukumoto, Keiichiro
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 469 - 475
反应条件
HBEA zeolite in nitrobenzene T=120°C; Rearrangement; 8 h; Product distribution; Further Variations:TemperaturesReaction partnerstime;
参考文献
Fromentin; Coustard; Guisnet
Journal of Catalysis, 2000 , vol. 190, # 2 p. 433 - 438
参考文献
Tobisu, Mamoru; Shimasaki, Toshiaki; Chatani, Naoto
Angewandte Chemie - International Edition, 2008 , vol. 47, # 26 p. 4866 - 4869
