(2R,3S,4S,5R,6S)-2-(羟基甲基)-6-[2-(4-甲基-1-环己-3-烯基)丙-2-基氧基]四氢吡喃-3,4,5-三醇合成路线 （共 4 条）
反应条件
sodium methylate in methanol
0.25 h; Ambient temperature;
参考文献
Yamahara; Kimura; Kobayashi; Okamoto; Sawada; Fujimura; Chisaka
Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 4 p. 1669 - 1675
反应条件
1: CaSO4, CF3COOAg, NaHCO3 / diethyl ether / 1 h / 0 °C
2: Amberlyst A-26 / methanol / 3 h / 20 °C
View Scheme
参考文献
Ackermann, Irmtraud E.; Banthorpe, Derek V.; Fordham, William D.; Kinder, John P.; Poots, Ian
Liebigs Annalen der Chemie, 1989 , p. 79 - 82
反应条件
1: CaSO4, CF3COOAg, NaHCO3 / diethyl ether / 1 h / 0 °C
2: Amberlyst A-26 / methanol / 3 h / 20 °C
View Scheme
参考文献
Ackermann, Irmtraud E.; Banthorpe, Derek V.; Fordham, William D.; Kinder, John P.; Poots, Ian
Liebigs Annalen der Chemie, 1989 , p. 79 - 82
反应条件
whole-cell of E. coli BL21 culture
T=25°C; pH=7.0; 72 h; aq. bufferEnzymatic reaction;
参考文献
Caputi, Lorenzo; Lim, Eng-Kiat; Bowles, Dianna J.
Chemistry - A European Journal, 2008 , vol. 14, # 22 p. 6656 - 6662
