(E)-辛-2-烯基乙酸酯合成路线 （共 18 条）
反应条件
1: With (2,2′-bipyridine)nickel(II) dibromide in N,N-dimethyl-formamide T=20°C; P=760.051 Torr; Electrolysis; 2: With potassium carbonate; methyl iodide in N,N-dimethyl-formamide T=60°C; 6 h; regioselective reaction;
参考文献
Medeiros; Pintaric; Olivero; Dunach
Electrochimica Acta, 2011 , vol. 56, # 11 p. 4384 - 4389
反应条件
dichloro bis(acetonitrile) palladium(II) in tetrahydrofuran 0.5 h; Yield given;
参考文献
Oehlschlager, A. C.; Mishra, P.; Dhami, S.
Canadian Journal of Chemistry, 1984 , vol. 62, p. 791 - 797
反应条件
toluene-4-sulfonic acid in acetic acid
1.) 30 min, 0 deg C, 2.) 15 min, room temperature;
参考文献
Vig, O. P.; Jindal, R. T.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 9 p. 919 - 920
反应条件
1: 1.) Fe(NO3)3, lithium metal / 1.) liquid ammonia, dry THF, 1 h, 2.) dry THF, 2 h
2: LAH / tetrahydrofuran / 5 h / Heating
3: p-toluenesulphonic acid / acetic acid / 1.) 30 min, 0 deg C, 2.) 15 min, room temperature
View Scheme
参考文献
Vig, O. P.; Jindal, R. T.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 9 p. 919 - 920
反应条件
1: LAH / tetrahydrofuran / 5 h / Heating
2: p-toluenesulphonic acid / acetic acid / 1.) 30 min, 0 deg C, 2.) 15 min, room temperature
View Scheme
参考文献
Vig, O. P.; Jindal, R. T.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 9 p. 919 - 920
参考文献
Naves
Helvetica Chimica Acta, 1943 , vol. 26, p. 1999
反应条件
dichloro bis(acetonitrile) palladium(II) in tetrahydrofuran
2 h; Yield given;
参考文献
Oehlschlager, A. C.; Mishra, P.; Dhami, S.
Canadian Journal of Chemistry, 1984 , vol. 62, p. 791 - 797
反应条件
in dichloromethane
Acetylation;
参考文献
Leal, Walter Scares; Ueda, Yasuo; Ono, Mikio
Journal of Chemical Ecology, 1996 , vol. 22, # 8 p. 1429 - 1437
反应条件
dichloro bis(acetonitrile) palladium(II) in tetrahydrofuran
T=31°C; 120 h; rate; Product distribution;
参考文献
Oehlschlager, A. C.; Mishra, P.; Dhami, S.
Canadian Journal of Chemistry, 1984 , vol. 62, p. 791 - 797
反应条件
sodium acetate
1.) CH3COOH, room temp., 2.) CH3COOH, 170 deg C, 3 d; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Garcia Martinez, Antonio; Oliver Ruiz, Manuel; Contelles, Jose Luis Marco
Synthesis, 1986 , # 1 p. 125 - 128
