2,2-偶氮(2,4,4-三甲基戊烷)合成路线 （共 7 条）
反应条件
in benzene T=200°C; 0.25 h;
参考文献
Fritzsche, Katharina; Beckhaus, Hans-Dieter; Ruechardt, Christoph
Tetrahedron Letters, 1988 , vol. 29, # 23 p. 2805 - 2808
反应条件
sodium hydroxide in water
T=80°C; 0.5 h;
参考文献
Timberlake, Jack W.; Alender, Jeff; Garner, Archie W.; Hodges, Melvin L.; Oezmeral, Cenan; et al.
Journal of Organic Chemistry, 1981 , vol. 46, # 10 p. 2082 - 2089
反应条件
(i) NaH, pentane, (ii) tBuOCl; Multistep reaction;
参考文献
Timberlake,J.W. et al.
Synthesis, 1972 , p. 632 - 634
反应条件
1: 82 percent / sodium hydride / tetrahydrofuran / 1.) -30 deg C, 2 h, 2.) 0 deg C, 1 h
2: 90 percent / 6 N NaOH / H2O / 0.5 h / 80 °C / var. reaction partners, var. conditions
View Scheme
参考文献
Timberlake, Jack W.; Alender, Jeff; Garner, Archie W.; Hodges, Melvin L.; Oezmeral, Cenan; et al.
Journal of Organic Chemistry, 1981 , vol. 46, # 10 p. 2082 - 2089
反应条件
pyridine; iodine pentafluoride in dichloromethane
参考文献
Prochazka,M.
Collection of Czechoslovak Chemical Communications, 1976 , vol. 41, p. 1557 - 1564
反应条件
1: Cl2 / petroleum ether
2: petroleum ether
View Scheme
参考文献
Duismann,W. et al.
Justus Liebigs Annalen der Chemie, 1974 , p. 1348 - 1356
参考文献
Duismann,W. et al.
Justus Liebigs Annalen der Chemie, 1974 , p. 1348 - 1356
