1: With benzo[1,3,2]dioxaborole; rhodium complex 2 in toluene T=20°C; Addition; Hydroboration; 2 h; 2: With sodium hydroxide; water; dihydrogen peroxide in toluene T=20°C; Oxidation; 2 h; Title compound not separated from byproducts;
参考文献
Doucet, Henri; Fernandez, Elena; Layzell, Timothy P.; Brown, John M.
Chemistry - A European Journal, 1999 , vol. 5, # 4 p. 1320 - 1330
1: With bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; (1R,2R)-1,2-bis(di[2-furyl]phosphanyl)cyclohexane; benzo[1,3,2]dioxaborole in ethylene glycol dimethyl ether; toluene T=-75°C; 1 h; 2: With potassium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether Title compound not separated from byproducts;
参考文献
Moteki, Shin A.; Takacs, James M.
Angewandte Chemie - International Edition, 2008 , vol. 47, # 5 p. 894 - 897
1: in carbon disulfide T=20°C; 5 h; 2: With sodium hydroxide; dihydrogen peroxide in methanol; carbon disulfide T=0 - 20°C; 3 h; Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Madhi, Sateesh; O'Donnell, Martin J.
Journal of Fluorine Chemistry, 2006 , vol. 127, # 9 p. 1252 - 1255
1H-imidazole; C84H72ClFeN4O12S4(4-)*4Na(1+); dihydrogen peroxide in methanol; water 1 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Maux, Paul Le; Srour, Hassan F.; Simonneaux, Gerard
Tetrahedron, 2012 , vol. 68, # 29 p. 5824 - 5828
