1: With bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; (1R,2R)-1,2-bis(di[2-furyl]phosphanyl)cyclohexane; benzo[1,3,2]dioxaborole in ethylene glycol dimethyl ether; toluene T=-75°C; 1 h; 2: With potassium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether Title compound not separated from byproducts;
参考文献
Moteki, Shin A.; Takacs, James M.
Angewandte Chemie - International Edition, 2008 , vol. 47, # 5 p. 894 - 897
1: With benzo[1,3,2]dioxaborole; rhodium complex 2 in toluene T=20°C; Addition; Hydroboration; 2 h; 2: With sodium hydroxide; water; dihydrogen peroxide in toluene T=20°C; Oxidation; 2 h; Title compound not separated from byproducts;
参考文献
Doucet, Henri; Fernandez, Elena; Layzell, Timothy P.; Brown, John M.
Chemistry - A European Journal, 1999 , vol. 5, # 4 p. 1320 - 1330
1: With bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; (1R,2R)-1,2-bis(di[2-furyl]phosphanyl)cyclohexane; benzo[1,3,2]dioxaborole in ethylene glycol dimethyl ether; toluene T=-75°C; 1 h; 2: With potassium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether Title compound not separated from byproducts;
参考文献
Moteki, Shin A.; Takacs, James M.
Angewandte Chemie - International Edition, 2008 , vol. 47, # 5 p. 894 - 897
1: With benzo[1,3,2]dioxaborole; rhodium complex 2 in toluene T=20°C; Addition; Hydroboration; 2 h; 2: With sodium hydroxide; water; dihydrogen peroxide in toluene T=20°C; Oxidation; 2 h; Title compound not separated from byproducts;
参考文献
Doucet, Henri; Fernandez, Elena; Layzell, Timothy P.; Brown, John M.
Chemistry - A European Journal, 1999 , vol. 5, # 4 p. 1320 - 1330
1: With bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; (1R,2R)-1,2-bis(di[2-furyl]phosphanyl)cyclohexane; benzo[1,3,2]dioxaborole in ethylene glycol dimethyl ether; toluene T=-75°C; 1 h; 2: With potassium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether Title compound not separated from byproducts;
参考文献
Moteki, Shin A.; Takacs, James M.
Angewandte Chemie - International Edition, 2008 , vol. 47, # 5 p. 894 - 897
1: With benzo[1,3,2]dioxaborole; rhodium complex 2 in toluene T=20°C; Addition; Hydroboration; 2 h; 2: With sodium hydroxide; water; dihydrogen peroxide in toluene T=20°C; Oxidation; 2 h; Title compound not separated from byproducts;
参考文献
Doucet, Henri; Fernandez, Elena; Layzell, Timothy P.; Brown, John M.
Chemistry - A European Journal, 1999 , vol. 5, # 4 p. 1320 - 1330
