2-苯基-2-环戊烯-1-酮合成路线 （共 43 条）
反应条件
4-methylmorpholine N-oxide in dichloromethane
T=20°C; Cycloaddition; Khand cycloadditions;
参考文献
Kerr, William J.; McLaughlin, Mark; Pauson, Peter L.; Robertson, Sarah M.
Journal of Organometallic Chemistry, 2001 , vol. 630, # 1 p. 104 - 117
反应条件
4-methylmorpholine N-oxide in dichloromethane
T=20°C; Cycloaddition; Khand cycloadditions;
参考文献
Kerr, William J.; McLaughlin, Mark; Pauson, Peter L.; Robertson, Sarah M.
Journal of Organometallic Chemistry, 2001 , vol. 630, # 1 p. 104 - 117
反应条件
(NH4)2S2O8; copper diacetate; sodium acetate in water; acetic acid
T=100°C; Yield given. Yields of byproduct given;
参考文献
Walling, Cheves; El-Taliawi, Gamil M.; Amarnath, Kalyani
Journal of the American Chemical Society, 1984 , vol. 106, p. 7573 - 7578
反应条件
4-methylmorpholine N-oxide in dichloromethane
T=20°C; Cycloaddition; Khand cycloadditions;
参考文献
Kerr, William J.; McLaughlin, Mark; Pauson, Peter L.; Robertson, Sarah M.
Journal of Organometallic Chemistry, 2001 , vol. 630, # 1 p. 104 - 117
反应条件
Co2Rh2 nanoparticles immobilized on charcoal in tetrahydrofuran
T=130°C; 18 h;
参考文献
Park, Kang Hyun; Jung, Il Gu; Chung, Young Keun
Organic Letters, 2004 , vol. 6, # 7 p. 1183 - 1186
反应条件
PdBr2(CH3CN)2; oxygen; caesium carbonate; (+)-sparteine surrogate in chloroform
T=20°C; 12 h; Molecular sieve; optical yield given as percent ee;
参考文献
Ebner, David C.; Trend, Raissa M.; Genet, Cedric; McGrath, Matthew J.; O'Brien, Peter; Stoltz, Brian M.
Angewandte Chemie - International Edition, 2008 , vol. 47, # 34 p. 6367 - 6370
反应条件
aluminium trichloride in chlorobenzene
2 h; Ambient temperature;
参考文献
Yamashita, Mitsuo; Onozuka, Junko; Tsuchihashi, Gen-ichi; Ogura, Katsuyuki
Tetrahedron Letters, 1983 , vol. 24, # 1 p. 79 - 82
反应条件
1: iodobenzene With n-butyllithium; zinc dibromide in tetrahydrofuran; hexane
T=-78 - 20°C;
2: 2-iodo-2-cyclopent-2-en-1-one With bis-triphenylphosphine-palladium(II) chloride; n-butyllithium in tetrahydrofuran; hexane; N,N-dimethyl-formamide
T=20°C; Negishi coupling; 5 h;
参考文献
Pour, Milan; Spulak, Marcel; Balsanek, Vojtech; Kunes, Jiri; Kubanova, Petra; Buchta, Vladimir
Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 13 p. 2843 - 2866
反应条件
chromium(VI) oxide; sulfuric acid in acetone
0.5 h;
参考文献
Decesare, John M.; Corbel, Bernard; Durst, Tony; Blount, John F.
Canadian Journal of Chemistry, 1981 , vol. 59, p. 1415 - 1424
反应条件
oxygen; caesium carbonate; (-)-sparteine in toluene; tert-butyl alcohol
T=60°C; P=760.051 Torr; 1.5 h; Molecular sieve; optical yield given as percent ee;
参考文献
Ebner, David C.; Bagdanoff, Jeffrey T.; Ferreira, Eric M.; McFadden, Ryan M.; Caspi, Daniel D.; Trend, Raissa M.; Stoltz, Brian M.
Chemistry - A European Journal, 2009 , vol. 15, # 47 p. 12978 - 12992
