1,3-二甲基-2-苯基苯合成路线 （共 66 条）
反应条件
palladium diacetate; tri-cyclo-hexyl-phosphine in ethylene glycol dimethyl ether
T=20°C; 3 h;
参考文献
Ku, Shih-Lun; Hui, Xin-Ping; Chen, Chien-An; Kuo, Yi-Ying; Gau, Han-Mou
Chemical Communications, 2007 , # 37 p. 3847 - 3849
反应条件
C46H55ClFeN3Pd; lithium chloride in tetrahydrofuran
T=60°C; Kumada coupling reaction; 12 h; Inert atmosphere;
参考文献
Ren, Gerui; Cui, Xiuling; Wu, Yangjie
European Journal of Organic Chemistry, 2010 , # 12 p. 2372 - 2378
反应条件
C46H55ClFeN3Pd; lithium chloride in tetrahydrofuran
T=60°C; Kumada coupling reaction; 24 h; Inert atmosphere;
参考文献
Ren, Gerui; Cui, Xiuling; Wu, Yangjie
European Journal of Organic Chemistry, 2010 , # 12 p. 2372 - 2378
反应条件
C26H16Cl6N2O2Pd2; tetrabutylammomium bromide; potassium hydroxide in methanol; water
T=110°C; Suzuki coupling; 0.333333 h; Microwave irradiation;
参考文献
Civicos, Jose Francisco; Alonso, Diego A.; Najera, Carmen
European Journal of Organic Chemistry, 2012 , # 19 p. 3670 - 3676
反应条件
tetrabutyl ammonium fluoride; triphenylphosphine; palladium diacetate in tetrahydrofuran; N,N-dimethyl-formamide
Heating;
参考文献
Riggleman, Shaundra; DeShong, Philip
Journal of Organic Chemistry, 2003 , vol. 68, # 21 p. 8106 - 8109
反应条件
caesium carbonate; tri-cyclo-hexyl-phosphine; palladium diacetate in tetrahydrofuran
Suzuki-Miyaura reaction; 72 h; Heating;
参考文献
Molander, Gary A.; Petrillo, Daniel E.; Landzberg, Nicole R.; Rohanna, John C.; Biolatto, Betina
Synlett, 2005 , # 11 art. no. Y00205ST, p. 1763 - 1766
反应条件
caesium carbonate; polystyrene-supported triphenylphosphine palladium in isopropyl alcohol
T=70°C; Suzuki-Miyaura reaction; 1 h;
参考文献
He, Helen Song; Yan, Jessie Jing; Shen, Ruxiang; Zhuo, Shangjun; Toy, Patrick H.
Synlett, 2006 , # 4 p. 563 - 566
反应条件
potassium tert-butylate in isopropyl alcohol
T=80°C; Suzuki-Miyaura coupling; 12 h; Inert atmosphere;
参考文献
Li, Guang; Yang, Hengquan; Li, Wei; Zhang, Guoliang
Green Chemistry, 2011 , vol. 13, # 10 p. 2939 - 2947
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate in chlorobenzene
T=80°C; Suzuki cross-coupling; P=760.051 Torr; 24 h; Inert atmosphere;
参考文献
Michael O'Keefe; Simmons, Nicholas; Martin, Stephen F.
Organic Letters, 2008 , vol. 10, # 22 p. 5301 - 5304
反应条件
1: diallyl(diphenyl)silane With tetrabutyl ammonium fluoride in water; dimethyl sulfoxide
T=20°C; 1 h;
2: 1-bromo-2,6-dimethyl-benzene With tri-cyclo-hexyl-phosphine; palladium dichloride in water; dimethyl sulfoxide
T=80°C; 24 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
