in gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. CF4; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;
antimony pentachloride in not given fluorination of PSCl3 with SbF3; addn. of SBF3 at 70-80 °C; ratio of products depending on pressure and temp.;; fractional distn., cooling agent liquid air or CO2-acetone;;
antimony pentachloride in not given fluorination of PSCl3 with SbF3; addn. of SBF3 at 70-80 °C; ratio of products depending on pressure and temp.;; fractional distn., cooling agent liquid air or CO2-acetone;;
参考文献
Industrial and Engineering Chemistry, , vol. 29, p. 470 - 475
