2-乙烯基-1,3-二氧戊环合成路线 （共 60 条）
反应条件
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide T=110°C; Heck reaction; 20 h; 2: With sodium hydroxide; water in N,N-dimethyl-formamide T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
参考文献
Hibbert; Whelen
Journal of the American Chemical Society, 1929 , vol. 51, p. 3119
反应条件
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide
T=110°C; Heck reaction; 20 h;
2: With sodium hydroxide; water in N,N-dimethyl-formamide
T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
反应条件
potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide
T=110°C; Heck reaction; 20 h;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
反应条件
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide
T=110°C; Heck reaction; 20 h;
2: With sodium hydroxide; water in N,N-dimethyl-formamide
T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
反应条件
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide
T=110°C; Heck reaction; 20 h;
2: With sodium hydroxide; water in N,N-dimethyl-formamide
T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
参考文献
Gassman, Paul G.; Singleton, Daniel A.; Wilwerding, James J.; Chavan, Subhash P.
Journal of the American Chemical Society, 1987 , vol. 109, # 7 p. 2182 - 2184
反应条件
sodium carbonate; 1,2-bis-(diphenylphosphino)ethane; palladium diacetate in DMF (N,N-dimethyl-formamide)
T=110°C; Heck Reaction; 23 h;
参考文献
LYMPHOSIGN INC.
Patent: WO2005/777 A2, 2005 ;
Location in patent: Page 21; 22 ;
反应条件
bis[(S,S,S)-DiazaPhos-SPE]; [rhodium(I)(carbonyl)2(acetylacetonate)]; hydrogen in tetrahydrofuran; toluene
T=40°C; P=8000.32 Torr; 4 h; optical yield given as percent eeenantioselective reaction;
参考文献
McDonald, Richard I.; Wong, Gene W.; Neupane, Ram P.; Stahl, Shannon S.; Landis, Clark R.
Journal of the American Chemical Society, 2010 , vol. 132, # 40 p. 14027 - 14029
反应条件
pyridinium p-toluenesulfonate in neat (no solvent)
T=200°C; 0.25 h;
参考文献
Coates, Robert M.; Hobbs, Steven J.
Journal of Organic Chemistry, 1984 , vol. 49, p. 140 - 152
