2-乙烯基-1,3-二氧戊环合成路线 （共 60 条）
反应条件
pyridinium p-toluenesulfonate in neat (no solvent)
T=200°C; 0.25 h;
参考文献
Coates, Robert M.; Hobbs, Steven J.
Journal of Organic Chemistry, 1984 , vol. 49, p. 140 - 152
反应条件
pyridinium p-toluenesulfonate in neat (no solvent)
T=200°C; 3.5 h;
参考文献
Coates, Robert M.; Hobbs, Steven J.
Journal of Organic Chemistry, 1984 , vol. 49, p. 140 - 152
反应条件
sulfuric acid in ethanol
14 h; Heating;
参考文献
Espinosa, Antonio; Gallo, Miguel A.; Campos, Joaquin
Bulletin de la Societe Chimique de France, 1983 , vol. 2, # 9-10 p. 265 - 268
反应条件
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide
T=110°C; Heck reaction; 20 h;
2: With sodium hydroxide; water in N,N-dimethyl-formamide
T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
反应条件
sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide
1) THF, 25 deg C, 2 h; Product distribution;
参考文献
Brown, Herbert C.; Chen, Jackson C.
Journal of Organic Chemistry, 1981 , vol. 46, # 20 p. 3978 - 3988
反应条件
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide
T=90°C; Heck reaction; 20 h;
2: With sodium hydroxide; water in N,N-dimethyl-formamide
T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
反应条件
C35H45N3O4Ru in tetrahydrofuran
T=35°C; 3 h; TimeReagent/catalyst; stereoselective reaction;
参考文献
Quigley, Brendan L.; Grubbs, Robert H.
Chemical Science, 2014 , vol. 5, # 2 p. 501 - 506
反应条件
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide
T=110°C; Heck reaction; 20 h;
2: With sodium hydroxide; water in N,N-dimethyl-formamide
T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
反应条件
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide
T=110°C; Heck reaction; 20 h;
2: With sodium hydroxide; water in N,N-dimethyl-formamide
T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
反应条件
bromine in chloroform
T=-70 - 20°C;
参考文献
Saygili, Nezire; Brown, R.James; Day, Peter; Hoelzl, Robert; Kathirgamanathan, Poopathy; Mageean, Eileen R; Ozturk, Turan; Pilkington, Melanie; Qayyum, Mohammed M.B; Turner, Scott S; Vorwerg, Lars; Wallis, John D
Tetrahedron, 2001 , vol. 57, # 23 p. 5015 - 5026
