1-甲基-2-(苯氧基)苯合成路线 （共 45 条）
反应条件
1: hydrogen; sodium t-butanolate; [Ni(CH2SiMe3)2(tmen)] / m-xylene / 48 h / 120 °C / 750.08 Torr / |Schlenk technique
2: pyridine-2-carboxylic acid; potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 20 h / 100 °C / |Inert atmosphere
View Scheme
参考文献
Sergeev, Alexey G.; Webb, Jonathan D.; Hartwig, John F.
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20226 - 20229
反应条件
1: hydrogen; sodium t-butanolate; [Ni(CH2SiMe3)2(tmen)] / m-xylene / 96 h / 120 °C / 750.08 Torr / |Schlenk technique
2: pyridine-2-carboxylic acid; potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 20 h / 100 °C / |Inert atmosphere
View Scheme
参考文献
Sergeev, Alexey G.; Webb, Jonathan D.; Hartwig, John F.
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20226 - 20229
反应条件
1: hydrogen; sodium t-butanolate; [Ni(CH2SiMe3)2(tmen)] / m-xylene / 48 h / 120 °C / 750.08 Torr / |Schlenk technique
2: pyridine-2-carboxylic acid; potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 20 h / 100 °C / |Inert atmosphere
View Scheme
参考文献
Sergeev, Alexey G.; Webb, Jonathan D.; Hartwig, John F.
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20226 - 20229
反应条件
1: pyridine-2-carboxylic acid; potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 24 h / 100 °C / |Inert atmosphere
2: hydrogen; sodium t-butanolate; [Ni(CH2SiMe3)2(tmen)] / m-xylene / 48 h / 120 °C / 750.08 Torr / |Schlenk technique
3: pyridine-2-carboxylic acid; potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 20 h / 100 °C / |Inert atmosphere
View Scheme
参考文献
Sergeev, Alexey G.; Webb, Jonathan D.; Hartwig, John F.
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20226 - 20229
反应条件
1: hydrogen; sodium t-butanolate; [Ni(CH2SiMe3)2(tmen)] / m-xylene / 48 h / 120 °C / 750.08 Torr / |Schlenk technique
2: pyridine-2-carboxylic acid; potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 20 h / 100 °C / |Inert atmosphere
View Scheme
参考文献
Sergeev, Alexey G.; Webb, Jonathan D.; Hartwig, John F.
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20226 - 20229
反应条件
1: hydrogen; sodium t-butanolate; [Ni0(1,5-cyclooctadiene)2] / m-xylene / 16 h / 120 °C / 775.74 Torr / |Schlenk technique
2: hydrogen; sodium t-butanolate; [Ni(CH2SiMe3)2(tmen)] / m-xylene / 48 h / 120 °C / 750.08 Torr / |Schlenk technique
3: pyridine-2-carboxylic acid; potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 20 h / 100 °C / |Inert atmosphere
View Scheme
参考文献
Sergeev, Alexey G.; Webb, Jonathan D.; Hartwig, John F.
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20226 - 20229
反应条件
1: hydrogen; sodium t-butanolate; [Ni(CH2SiMe3)2(tmen)] / m-xylene / 48 h / 120 °C / 750.08 Torr / |Schlenk technique
2: pyridine-2-carboxylic acid; potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 20 h / 100 °C / |Inert atmosphere
View Scheme
参考文献
Sergeev, Alexey G.; Webb, Jonathan D.; Hartwig, John F.
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20226 - 20229
反应条件
1: hydrogen; sodium t-butanolate; [Ni(CH2SiMe3)2(tmen)] / m-xylene / 48 h / 120 °C / 750.08 Torr / |Schlenk technique
2: pyridine-2-carboxylic acid; potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 20 h / 100 °C / |Inert atmosphere
View Scheme
参考文献
Sergeev, Alexey G.; Webb, Jonathan D.; Hartwig, John F.
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20226 - 20229
反应条件
ortho-cresol
T=200 - 220°C;
参考文献
Fritzsche and Co.
Patent: DE269543 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 11, p. 184
反应条件
1: 4-(N,N-dimethlyamino)pyridine; triethylamine / dichloromethane / 15 h / 20 °C / |Schlenk technique; |Inert atmosphere
2: [Ni0(1,5-cyclooctadiene)2]; dcype; caesium carbonate / anhydrous xylene / 72 h / 160 °C
View Scheme
参考文献
Wang, Jiayi; Ferguson, Devin M.; Kalyani, Dipannita
Tetrahedron, 2013 , vol. 69, # 27-28 p. 5780 - 5790
