3,4-二氯苯硼酸频那醇酯合成路线 （共 16 条）
反应条件
tert.-butylnitrite in acetonitrile T=80°C; 2 h;
参考文献
Qiu, Di; Jin, Liang; Zheng, Zhitong; Meng, He; Mo, Fanyang; Wang, Xi; Zhang, Yan; Wang, Jianbo
Journal of Organic Chemistry, 2013 , vol. 78, # 5 p. 1923 - 1933
反应条件
C2F3O2(1-)*C21H34IrN4(1+) T=180°C; 0.5 h; Microwave irradiationNeat (no solvent);
参考文献
Rentzsch, Christoph F.; Tosh, Evangeline; Herrmann, Wolfgang A.; Kuehn, Fritz E.
Green Chemistry, 2009 , vol. 11, # 10 p. 1610 - 1617
反应条件
1: tBuCH2CH2B(H)NiPr2; 1,2-dichloro-4-diazoniumbenzene tetrafluoroborate With bis(cyclopentadienyl)titanium dichloride in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; Reagent/catalyst;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 53-54; 67-68 ;
反应条件
[Ir(OMe)(1,5-cyclooctadiene)]2 in benzene T=80°C; 12 h; Schlenk techniqueInert atmosphere; regioselective reaction;
参考文献
Waki, Minoru; Maegawa, Yoshifumi; Hara, Kenji; Goto, Yasutomo; Shirai, Soichi; Yamada, Yuri; Mizoshita, Norihiro; Tani, Takao; Chun, Wang-Jae; Muratsugu, Satoshi; Tada, Mizuki; Fukuoka, Atsushi; Inagaki, Shinji
Journal of the American Chemical Society, 2014 , vol. 136, # 10 p. 4003 - 4011
反应条件
in diethyl ether T=20°C; 17 h;
参考文献
Roesner, Stefan; Casatejada, Javier Mansilla; Elford, Tim G.; Sonawane, Ravindra P.; Aggarwal, Varinder K.
Organic Letters, 2011 , vol. 13, # 21 p. 5740 - 5743
反应条件
in diethyl ether T=20°C; 4 h; Inert atmosphere;
参考文献
Marciasini, Ludovic D.; Richy, Nicolas; Vaultier, Michel; Pucheault, Mathieu
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 6 p. 1083 - 1088
反应条件
in cyclohexane (Schlenk; N2 atm.) a soln. of complex and 60 equiv of dichlorobenzene incyclohexane was stirred; not sepd., detected by NMR and mass-spectra;
参考文献
Boller, Timothy M.; Murphy, Jaclyn M.; Hapke, Marko; Ishiyama, Tatsuo; Miyaura, Norio; Hartwig, John F.
Journal of the American Chemical Society, 2005 , vol. 127, # 41 p. 14263 - 14278
反应条件
in cyclohexane T=20°C;
参考文献
Boller, Timothy M.; Murphy, Jaclyn M.; Hapke, Marko; Ishiyama, Tatsuo; Miyaura, Norio; Hartwig, John F.
Journal of the American Chemical Society, 2005 , vol. 127, # 41 p. 14263 - 14278
反应条件
[Ir(C8H12)(OCH3)]2; 4,4'-di-tertbutylpyridine in further solvent(s) (N2); heating mixt. of iridium compd., bipyridine deriv., benzene deriv., dodecane and silylborane deriv. at 80°C for 4 h; cooling to room temp., chromy. (silica gel, diethyl ether in hexane (gradient from 0percent to 5percent)), NMR;
参考文献
Boebel, Timothy A.; Hartwig, John F.
Organometallics, 2008 , vol. 27, # 22 p. 6013 - 6019
反应条件
bis(4,4,5,5-(CH3)4-1,3,2-dioxaborolanyl)-d24 in benzene-d6; perdeuterocyclohexane Kinetics; (Schlenk; N2 atm.) a soln. of complex in cyclohexane-d12 was frozen in NMR tube, dioxaborolanyl-d24 in C6D6 was added, 1,2-dichlorobenzene was added at 0°C; not sepd., detected by NMR spectra at 7.5°C;
参考文献
Boller, Timothy M.; Murphy, Jaclyn M.; Hapke, Marko; Ishiyama, Tatsuo; Miyaura, Norio; Hartwig, John F.
Journal of the American Chemical Society, 2005 , vol. 127, # 41 p. 14263 - 14278
