反应条件
1: 83 percent / Ph3P, Br2 / CCl4 / 3 h
2: 1.) Mg / 1.) THF, from 45 deg C to 50 deg C, 2.) THF, RT, 0.5 h
3: tetrahydrofuran / 1 h / Ambient temperature
4: O3 / cyclohexane; acetic acid / 5 °C
5: aq. H2CrO4 / cyclohexane; acetic acid / 4 h / 20 °C
6: 94 percent / K2CO3 / methanol / 2 h / 50 °C
View Scheme
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Botsman, L. P.; Vakhidov, R. R.; Khametova, R. R.; et al.
Chemistry of Natural Compounds, 1992 , vol. 28, # 3/4 p. 365 - 369
Khimiya Prirodnykh Soedinenii, 1992 , # 3,4 p. 417 - 422
