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乙二醇
甲醛
63148-62-9
MDI
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二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
对溴三氟甲苯
合成路线
（共 454 条）
402-43-7
对溴三氟甲苯
→
反应条件
119757-51-6
反应条件
1: 12 percent / triethylamine; CuI / Pd(PPh3)2Cl2 / 24 deg C, then 65 deg C 2: 49 percent / Mo(CO)6, 4-chlorophenol / various solvent(s) / 140 °C View Scheme
参考文献
Pschirer, Neil Gregory; Bunz, Uwe H. F.
Tetrahedron Letters, 1999 , vol. 40, # 13 p. 2481 - 2484
402-43-7
对溴三氟甲苯
+
142-45-0
丁炔二酸
→
反应条件
119757-51-6
反应条件
bis-triphenylphosphine-palladium(II) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-di(diphenylphosphino)-butane in dimethyl sulfoxide T=110°C; 6 h;
参考文献
Peng, Shiyong; Wang, Lei; Huang, Jiayao; Sun, Shaofa; Guo, Haibing; Wang, Jian
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 13 p. 2550 - 2557
100-70-9
2-氰基吡啶
+
402-43-7
对溴三氟甲苯
→
反应条件
122377-19-9
反应条件
1: 1-trifluoromethyl-4-bromobenzene With magnesium in tetrahydrofuran Inert atmosphere; 2: 2-pyridine carbonitrile in tetrahydrofuran T=0°C; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether 0.5 h; Inert atmosphere;
参考文献
Tao, Xiaoming; Li, Wanfang; Ma, Xin; Li, Xiaoming; Fan, Weizheng; Xie, Xiaomin; Ayad, Tahar; Ratovelomanana-Vidal, Virginie; Zhang, Zhaoguo
Journal of Organic Chemistry, 2012 , vol. 77, # 1 p. 612 - 616
930-68-7
+
402-43-7
对溴三氟甲苯
→
反应条件
122902-06-1
反应条件
1: 1-trifluoromethyl-4-bromobenzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.5 h; Inert atmosphere; 2: With indium(III) chloride in tetrahydrofuran; hexane T=-78 - 20°C; 4 h; Inert atmosphere; 3: cyclohexenon With methanol; [RhCl(η2:η2-cycloocta-1,5-diene)]2; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in tetrahydrofuran; hexane T=110°C; Inert atmosphere;
参考文献
Tato, Ruben; Riveiros, Ricardo; Perez Sestelo, Jose; Sarandeses, Luis A.
Tetrahedron, 2012 , vol. 68, # 5 p. 1606 - 1611
402-43-7
对溴三氟甲苯
→
反应条件
122902-06-1
反应条件
1: 1.) n-BuLi / 1.) Et2O, hexane, 0 deg C, 30 min, 2.) 0 deg C, 2 h 2: 1.) H2, 2.) Jones reagent / 1.) 10percent Pd/C / 1.) EtOAc, 30 psi, 8 h View Scheme
参考文献
Cieplak, Andrzej S.; Tait, Bradley D.; Johnson, Carl R.
Journal of the American Chemical Society, 1989 , vol. 111, # 22 p. 8447 - 8462
6165-68-0
+
402-43-7
对溴三氟甲苯
→
反应条件
115933-15-8
反应条件
potassium phosphate; [5-(3-butylbenzimidazol-2-yliden-1-yl)-25,26,27,28-tetrapropyloxy calix[4]arene] (pyridine) palladium(II) dibromide in 1,4-dioxane T=100°C; 24 h; Inert atmosphere;
参考文献
Ren, Hui; Xu, Yong; Jeanneau, Erwann; Bonnamour, Isabelle; Tu, Tao; Darbost, Ulrich
Tetrahedron, 2014 , vol. 70, # 17 p. 2829 - 2837
1003-09-4
+
402-43-7
对溴三氟甲苯
→
反应条件
115933-15-8
反应条件
1: 1-trifluoromethyl-4-bromobenzene With magnesium in tetrahydrofuran 1 h; Inert atmosphere; 2: thien-2-yl bromide With [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in tetrahydrofuran T=0 - 5°C; 12 h; Inert atmosphereReflux;
参考文献
Tokyo Institute of Technology; Kuraray Co., Ltd.
Patent: EP2511278 A1, 2012 ;
Location in patent: Page/Page column 11-12 ;
402-43-7
对溴三氟甲苯
+
197009-90-8
→
反应条件
115933-15-8
反应条件
sodium hydride; tri(tert-butyl)phosphine palladium complex in toluene T=50°C; 3 h;
参考文献
Denmark, Scott E.; Baird, John D.; Regens, Christopher S.
Journal of Organic Chemistry, 2008 , vol. 73, # 4 p. 1440 - 1455
402-43-7
对溴三氟甲苯
+
136768-52-0
→
反应条件
115933-15-8
反应条件
Pd0(tris(tert-butyl)phosphine)2 in N,N-dimethyl-formamide T=23 - 170°C; 0.141667 h; Microwave irradiation;
参考文献
Sevigny, Stephane; Forgione, Pat
Chemistry - A European Journal, 2013 , vol. 19, # 7 p. 2256 - 2260
→
反应条件
115933-15-8
反应条件
tri-tert-butylphosphine-based palladium catalyst in toluene T=50°C; 3 h;
参考文献
Denmark, Scott E.; Baird, John D.
Organic Letters, 2006 , vol. 8, # 4 p. 793 - 795
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