1,2,3,4-二-O-异亚丙基-alpha-D-岩藻吡喃糖合成路线 (共 31 条)
反应条件
2,2'-azo-bisisobutyronitrile; tris-(trimethylsilyl)silane in toluene T=130°C; Barton-McCombie deoxygenation; 0.0833333 h;
参考文献
Odedra, Arjan; Geyer, Karolin; Gustafsson, Tomas; Gilmour, Ryan; Seeberger, Peter H.
Chemical Communications, 2008 , # 26 p. 3025 - 3027
反应条件
tert-butylisonitrile; boron trifluoride in toluene T=20°C;
参考文献
Benati, Luisa; Leardini, Rino; Minozzi, Matteo; Nanni, Daniele; Scialpi, Rosanna; Spagnolo, Piero; Strazzari, Samantha; Zanardi, Giuseppe
Angewandte Chemie - International Edition, 2004 , vol. 43, # 27 p. 3598 - 3601
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride T=90°C; Barton-McCombie Deoxygenation; 2 h; Inert atmosphere; SolventTime;
参考文献
Kobayashi, Shoji; Kuroda, Hiroyuki; Ohtsuka, Yuta; Kashihara, Takashi; Masuyama, Araki; Watanabe, Kiyoshi
Tetrahedron, 2013 , vol. 69, # 10 p. 2251 - 2259
反应条件
lithium triethylborohydride in tetrahydrofuran Heating;
参考文献
Thiem; Meyer
Chemische Berichte, 1980 , vol. 113, # 9 p. 3067 - 3074
反应条件
triethylsilane; meta-chloroperoxybenzoic acid in toluene 2 h; Heating;
参考文献
Barton; Jang; Jaszberenyi Cs.
Tetrahedron, 1993 , vol. 49, # 14 p. 2793 - 2804
反应条件
hypophosphorous acid; triethylamine; Vazo44 in isopropyl alcohol T=80°C; 0.5 h;
参考文献
Nambu, Hisanori; Alinejad, Anahita Hessamian; Hata, Kayoko; Fujioka, Hiromichi; Kita, Yasuyuki
Tetrahedron Letters, 2004 , vol. 45, # 48 p. 8927 - 8929
反应条件
1: pyridine / 1 h / 20 °C 2: dimethylformamide / 10 h / 50 °C 3: LAH / tetrahydrofuran / 0.5 h / 0 °C 4: 95 percent / tert-butyl isonitrile; BF3 / toluene / 20 °C View Scheme
参考文献
Oba, Makoto; Nishiyama, Kozaburo
Tetrahedron, 1994 , vol. 50, # 34 p. 10193 - 10200
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in toluene T=111°C; 1.33333 h;
参考文献
Barton, Derek H. R.; Blundell, Paul; Dorchak, Joseph; Jang, Doo Ok; Jaszberenyi, Joseph Cs.
Tetrahedron, 1991 , vol. 47, # 43 p. 8969 - 8984
反应条件
tri-n-butyl-tin hydride in toluene 15 h; RefluxInert atmosphereSchlenk technique;
参考文献
Kopitzki, Sebastian; Dilmaghani, Karim Akbari; Thiem, Joachim
Tetrahedron, 2013 , vol. 69, # 49 p. 10621 - 10636
反应条件
sodium tetrahydroborate in acetonitrile 48 h; Ambient temperature;
参考文献
Barrette, Ernie-Paul; Goodman, Leon
Journal of Organic Chemistry, 1984 , vol. 49, # 1 p. 176 - 178