2-二苯基磷-2'-甲基联苯合成路线 （共 10 条）
反应条件
palladium diacetate; potassium phosphate in water; toluene T=100°C; Suzuki coupling; 10 h;
参考文献
Joshaghani, Mohammad; Daryanavard, Marzieh; Rafiee, Ezzat; Nadri, Shirin
Journal of Organometallic Chemistry, 2008 , vol. 693, # 19 p. 3135 - 3140
反应条件
trichlorosilane; triethylamine in toluene T=120°C;
参考文献
Baillie, Colin; Chen, Weiping; Xiao, Jianliang
Tetrahedron Letters, 2001 , vol. 42, # 51 p. 9085 - 9088
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Baillie, Colin; Xiao, Jianliang
Tetrahedron, 2004 , vol. 60, # 19 p. 4159 - 4168
反应条件
1: 92 percent / NaOAc / Pd(OAc)2 / N,N-dimethyl-acetamide / 72 h / 130 °C 2: 100 percent / H2O2 / methanol / 1 h / 20 °C 3: 74 percent / PPh3; K3PO4 / Pd(dba)2 / dioxane / 48 h / 105 °C 4: 71 percent / trichlorosilane; triethylamine / toluene / 120 °C View Scheme
参考文献
Brauer, David J.; Hingst, Martin; Kottsieper, Konstantin W.; Liek, Christian; Nickel, Thomas; Tepper, Michael; Stelzer, Othmar; Sheldrick, William S.
Journal of Organometalic Chemistry, 2002 , vol. 645, # 1-2 p. 14 - 26
反应条件
1: 74 percent / K3PO4 / Pd(dba)2; PPh3 / dioxane / 48 h / 105 °C 2: 71 percent / trichlorosilane; triethylamine / toluene / 120 °C View Scheme
参考文献
Zhang, Heng; Hu, Rong-Bin; Zhang, Xiao-Yu; Li, Shi-Xia; Yang, Shang-Dong
Chemical Communications, 2014 , vol. 50, # 36 p. 4686 - 4689
反应条件
1: 74 percent / PPh3; K3PO4 / Pd(dba)2 / dioxane / 48 h / 105 °C 2: 71 percent / trichlorosilane; triethylamine / toluene / 120 °C View Scheme
参考文献
Baillie, Colin; Chen, Weiping; Xiao, Jianliang
Tetrahedron Letters, 2001 , vol. 42, # 51 p. 9085 - 9088
反应条件
1: 65 percent / 1,3-bis(diphenylphosphino)propane; (i-Pr)2NEt / Pd(dba)2 / toluene / 96 h / 120 °C 2: 74 percent / PPh3; K3PO4 / Pd(dba)2 / dioxane / 48 h / 105 °C 3: 71 percent / trichlorosilane; triethylamine / toluene / 120 °C View Scheme
参考文献
Baillie, Colin; Xiao, Jianliang
Tetrahedron, 2004 , vol. 60, # 19 p. 4159 - 4168
反应条件
1: 92 percent / NaOAc / Pd(OAc)2 / N,N-dimethyl-acetamide / 72 h / 130 °C 2: 100 percent / H2O2 / methanol / 1 h / 20 °C 3: 74 percent / PPh3; K3PO4 / Pd(dba)2 / dioxane / 48 h / 105 °C 4: 71 percent / trichlorosilane; triethylamine / toluene / 120 °C View Scheme
参考文献
Brauer, David J.; Hingst, Martin; Kottsieper, Konstantin W.; Liek, Christian; Nickel, Thomas; Tepper, Michael; Stelzer, Othmar; Sheldrick, William S.
Journal of Organometalic Chemistry, 2002 , vol. 645, # 1-2 p. 14 - 26
反应条件
1: 100 percent / H2O2 / methanol / 1 h / 20 °C 2: 74 percent / PPh3; K3PO4 / Pd(dba)2 / dioxane / 48 h / 105 °C 3: 71 percent / trichlorosilane; triethylamine / toluene / 120 °C View Scheme
参考文献
Baillie, Colin; Xiao, Jianliang
Tetrahedron, 2004 , vol. 60, # 19 p. 4159 - 4168
反应条件
1: 2-bromo-2'-methylbiphenyl With n-butyllithium in diethyl ether; hexane T=0°C; 2 h; 2: Ph2P-Hal in diethyl ether; hexane T=20°C; 1 h;
参考文献
Hu, Rong-Bin; Zhang, Heng; Zhang, Xiao-Yu; Yang, Shang-Dong
Chemical Communications, 2014 , vol. 50, # 17 p. 2193 - 2195
反应条件
1: 2-bromo-2'-methylbiphenyl With n-butyllithium in diethyl ether; hexane T=0°C; 2 h; Inert atmosphere; 2: chloro-diphenylphosphine in diethyl ether; hexane T=20°C; 1 h; Inert atmosphere;
参考文献
Zhang, Heng; Hu, Rong-Bin; Zhang, Xiao-Yu; Li, Shi-Xia; Yang, Shang-Dong
Chemical Communications, 2014 , vol. 50, # 36 p. 4686 - 4689
