2,2',6,6'-四甲基联苯合成路线 （共 23 条）
反应条件
C54H80Cl2Fe2N2O4 in diethyl ether
T=22°C; 0.5 h; Inert atmosphere;
参考文献
Qian, Xin; Dawe, Louise N.; Kozak, Christopher M.
Dalton Transactions, 2011 , vol. 40, # 4 p. 933 - 943
反应条件
1: 2,4,6-trimethylphenylmagnesium bromide With PEPPSITM-IPr; zinc(II) chloride in tetrahydrofuran
T=23°C; 0.333333 h; Inert atmosphere;
2: 1-bromo-2,6-dimethyl-benzene in tetrahydrofuran
T=70°C; 2.5 h; Inert atmosphere;
参考文献
Calimsiz, Selcuk; Sayah, Mahmoud; Mallik, Debasis; Organ, Michael G.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 11 p. 2014 - 2017
反应条件
1: potassium hydroxide / toluene / 4 h / Reflux
2: palladium diacetate; BIPHEP; copper(l) chloride / N,N-dimethyl-formamide / 14 h / 80 °C / Inert atmosphere
View Scheme
参考文献
Li, Gao-Qiang; Yamamoto, Yasunori; Miyaura, Norio
Synlett, 2011 , # 12 p. 1769 - 1773
