1,1-二甲基硅杂环己烷合成路线 （共 27 条）
反应条件
magnesium; ethylene dibromide in dibutyl diglyme T=20 - 95°C; Grignard Reaction; 2 h;
参考文献
STARFIRE SYSTEMS, INC.
Patent: WO2008/33980 A2, 2008 ;
Location in patent: Page/Page column 11-12 ;
反应条件
di-tert-butyl peroxide in benzene T=145°C; 4 h;
参考文献
Barton,T.J.; Revis,A.
Journal of the American Chemical Society, 1984 , vol. 106, p. 3802
反应条件
1: 1,5-dibromo-pentane With magnesium in diethyl ether; ethylene dibromide 16 h; Reflux; 2: dimethyl-dichlorosilane in diethyl ether; ethylene dibromide 20 h; Reflux;
参考文献
Horn, Markus; Schappele, Ludwig H.; Lang-Wittkowski, Gabriele; Mayr, Herbert; Ofial, Armin R.
Chemistry - A European Journal, 2013 , vol. 19, # 1 p. 249 - 263
反应条件
in diethyl ether T=20 - 35°C; Industry scale;
参考文献
DOW CORNING CORPORATION
Patent: WO2009/61581 A1, 2009 ;
Location in patent: Page/Page column 9-10 ;
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in various solvent(s) T=25°C; Irradiation;
参考文献
Wilt, James W.
Journal of the American Chemical Society, 1981 , vol. 103, # 17 p. 5251 - 5253
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in various solvent(s) T=25°C; Irradiation;
参考文献
Wilt, James W.
Journal of the American Chemical Society, 1981 , vol. 103, # 17 p. 5251 - 5253
反应条件
tetraethylammonium bromide in tetrahydrofuran; N,N-dimethyl-formamide electrolysis;
参考文献
Jouikov, V.; Krasnov, V.
Journal of Organometallic Chemistry, 1995 , vol. 498, # 2 p. 213 - 220
反应条件
1: 70 percent / Mg / tetrahydrofuran / 8 h 2: 19 percent Chromat. / di-tert-butyl peroxide / benzene / 4 h / 145 °C View Scheme
参考文献
Barton,T.J.; Revis,A.
Journal of the American Chemical Society, 1984 , vol. 106, p. 3802
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in various solvent(s) T=25°C; 3 h; Irradiation;
参考文献
Wilt, James W.
Tetrahedron, 1985 , vol. 41, # 19 p. 3979 - 4000
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in various solvent(s) T=25°C; 3 h; Irradiation;
参考文献
Wilt, James W.
Tetrahedron, 1985 , vol. 41, # 19 p. 3979 - 4000
