1: With bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; (1R,2R)-1,2-bis(dicyclohexylphosphanyl)cyclohexane; benzo[1,3,2]dioxaborole in ethylene glycol dimethyl ether T=-35°C; 3 h; 2: With potassium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether Title compound not separated from byproducts;
参考文献
Segarra, Anna M.; Guirado, Francesc; Claver, Carmen; Fernandez, Elena
Tetrahedron Asymmetry, 2003 , vol. 14, # 12 p. 1611 - 1615
1: With benzo[1,3,2]dioxaborole; rhodium complex 2 in toluene T=20°C; Addition; Hydroboration; 2 h; 2: With sodium hydroxide; water; dihydrogen peroxide in toluene T=20°C; Oxidation; 2 h; Title compound not separated from byproducts;
参考文献
Moteki, Shin A.; Wu, Di; Chandra, Kusum L.; Sahadeva Reddy; Takacs, James M.
Organic Letters, 2006 , vol. 8, # 14 p. 3097 - 3100
1: With bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; (1R,2R)-1,2-bis(dicyclohexylphosphanyl)cyclohexane; benzo[1,3,2]dioxaborole in ethylene glycol dimethyl ether T=-35°C; 3 h; 2: With potassium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether Title compound not separated from byproducts;
参考文献
Segarra, Anna M.; Guirado, Francesc; Claver, Carmen; Fernandez, Elena
Tetrahedron Asymmetry, 2003 , vol. 14, # 12 p. 1611 - 1615
