sodium acetate T=180°C; Erwaermen des Reaktionsprodukts mit wss.-methanol. Salzsaeure;

1: 490 mg / H2 / 5percent palladium-charcoal / ethyl acetate 2: 10.6 g / pyridine / 3.25 h / 80 - 90 °C 3: 12.52 g / N-bromosuccinimide / CCl4 / 0.58 h / Heating 4: acetonitrile / 2 h / Heating 5: triethylamine / toluene / 1.) reflux, 4 h, 2.) room temperature, 12 h 6: 90 percent / LiALH4 / diethyl ether / 0.75 h / Ambient temperature 7: 73 percent / potassium nitrosodisulphonate, AcONa / H2O; methanol / 0.5 h View Scheme

sodium hydroxide; dihydrogen peroxide

暂无反应条件数据

hydrogen; palladium on activated charcoal in ethyl acetate

1: 490 mg / H2 / 5percent palladium-charcoal / ethyl acetate 2: 10.6 g / pyridine / 3.25 h / 80 - 90 °C View Scheme

1: 490 mg / H2 / 5percent palladium-charcoal / ethyl acetate 2: 10.6 g / pyridine / 3.25 h / 80 - 90 °C 3: 12.52 g / N-bromosuccinimide / CCl4 / 0.58 h / Heating View Scheme

1: 490 mg / H2 / 5percent palladium-charcoal / ethyl acetate 2: 10.6 g / pyridine / 3.25 h / 80 - 90 °C 3: 12.52 g / N-bromosuccinimide / CCl4 / 0.58 h / Heating 4: acetonitrile / 2 h / Heating 5: triethylamine / toluene / 1.) reflux, 4 h, 2.) room temperature, 12 h View Scheme

1: 490 mg / H2 / 5percent palladium-charcoal / ethyl acetate 2: 10.6 g / pyridine / 3.25 h / 80 - 90 °C 3: 12.52 g / N-bromosuccinimide / CCl4 / 0.58 h / Heating 4: acetonitrile / 2 h / Heating 5: triethylamine / toluene / 1.) reflux, 4 h, 2.) room temperature, 12 h 6: 90 percent / LiALH4 / diethyl ether / 0.75 h / Ambient temperature View Scheme