1: With triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran T=70°C; Negishi coupling reaction; 48 h; 2: With hydrogenchloride in tetrahydrofuran T=20°C; 24 h;
1: With triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in toluene T=110°C; Stille coupling reaction; 24 h; 2: With hydrogenchloride in toluene T=20°C; 24 h;
1: With triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran T=70°C; Negishi coupling reaction; 48 h; 2: With hydrogenchloride in tetrahydrofuran T=20°C; 24 h;
manganese(IV) oxide in chloroform 48 h; Ambient temperature;
参考文献
Baradarani, M. Mehdi; Dalton, Lesley; Heatley, Frank; Cohylakis, Demetrios; Joule, John A.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1503 - 1508
1: 1./ n-butyllithium / 1./ tetrahydrofuran, diethyl ether, -70 gradC, 30 min. 2./ tetrahydrofuran, diethyl ether, 15 min. 2: 0.24 g / manganese dioxide / CHCl3 / 48 h / Ambient temperature View Scheme
参考文献
Baradarani, M. Mehdi; Dalton, Lesley; Heatley, Frank; Cohylakis, Demetrios; Joule, John A.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1503 - 1508
