2,2,2-三氟乙酸乙酯合成路线 （共 25 条）
反应条件
dm-3 phosphate buffer T=25°C; pH 11.60; var. conc. of TFE, also in the presence of cyclodextrins at var conc.; Rate constant;
参考文献
Tee; Yazbeck
Canadian Journal of Chemistry, 2000 , vol. 78, # 8 p. 1100 - 1108
反应条件
lipase A from candida antarctica immobilized on Celite in di-isopropyl ether Enzymatic reaction; optical yield given as percent ee;
参考文献
Arkivoc, , vol. 2012, # 5 p. 60 - 74
反应条件
chirazyme L5; immobilised Candida antarctica lipase A in various solvent(s) T=23 - 24°C; 49 h;
参考文献
Lundell, Katri; Lehtinen, Petka; Kanerva, Liisa T.
Advanced Synthesis and Catalysis, 2003 , vol. 345, # 6-7 p. 790 - 796
反应条件
Novozym 435; potassium tert-butylate; sodium carbonate; [2,3,4,5-Ph4(η5-C4CNH(i-Pr))]Ru(CO)2Cl in toluene T=25°C; 96 h;
参考文献
Choi, Jun Ho; Choi, Yoon Kyung; Kim, Yu Hwan; Park, Eun Sil; Kim, Eun Jung; Kim, Mahn-Joo; Park, Jaiwook
Journal of Organic Chemistry, 2004 , vol. 69, # 6 p. 1972 - 1977
反应条件
Burkholderia cepacia lipase; C13H24N3(1+)*C36H73O14S(1-) in di-isopropyl ether T=35°C; 0.5 h; Kinetics; Reagent/catalystTime; optical yield given as percent eeenantioselective reaction;
参考文献
Abe, Yoshikazu; Hirakawa, Takuya; Nakajima, Shino; Okano, Nagisa; Hayase, Shuichi; Kawatsura, Motoi; Hirose, Yoshihiko; Itoh, Toshiyuki
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 13 p. 1954 - 1958
反应条件
methanol; tetra(n-butyl)ammonium hydroxide; zinc trifluoromethanesulfonate; 1,5,9-triaza-cyclododecane in acetonitrile T=25°C; pH=9.1; Kinetics; Further Variations:ReagentspH-values;
参考文献
Neverov, Alexei A.; Sunderland; Brown, R. Stan
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 1 p. 65 - 72
反应条件
Novozym 435; potassium tert-butylate; sodium carbonate; [2,3,4,5-Ph4(η5-C4CNH(i-Pr))]Ru(CO)2Cl in toluene T=25°C; 96 h;
参考文献
Choi, Jun Ho; Choi, Yoon Kyung; Kim, Yu Hwan; Park, Eun Sil; Kim, Eun Jung; Kim, Mahn-Joo; Park, Jaiwook
Journal of Organic Chemistry, 2004 , vol. 69, # 6 p. 1972 - 1977
反应条件
Burkholderia cepacia lipase; C13H24N3(1+)*C36H73O14S(1-) in di-isopropyl ether T=35°C; 0.5 h; Kinetics; Reagent/catalystTime; optical yield given as percent eeenantioselective reaction;
参考文献
Abe, Yoshikazu; Hirakawa, Takuya; Nakajima, Shino; Okano, Nagisa; Hayase, Shuichi; Kawatsura, Motoi; Hirose, Yoshihiko; Itoh, Toshiyuki
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 13 p. 1954 - 1958
反应条件
in toluene T=650°C; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 56, # 18 p. 846 - 849
反应条件
Lipase from Burkholderia cepacia in toluene T=22°C; 30 h; Molecular sieve; enantioselective reaction;
参考文献
Hietanen, Ari; Saloranta, Tiina; Leino, Reko; Kanerva, Liisa T.
Tetrahedron Asymmetry, 2012 , vol. 23, # 24 p. 1629 - 1632
