(Z)-8-十二烯-1-醇合成路线 （共 30 条）
反应条件
1: N2H4*H2O / bis-(2-hydroxy-ethyl) ether; methanol
2: LiAlH4
3: NH2CH2CH2NH2 / Ni catalyst / ethanol
View Scheme
参考文献
Mori; Uchida; Matsui
Tetrahedron, 1977 , vol. 33, # 4 p. 385 - 387
反应条件
1: NaH / dimethylsulfoxide
2: LiAlH4 / diethyl ether
3: H2 / Lindlar catalyst / methanol
View Scheme
参考文献
Kovaleva,A.S. et al.
Journal of Organic Chemistry USSR (English Translation), 1972 , vol. 8, p. 2523 - 2527
Zhurnal Organicheskoi Khimii, 1972 , vol. 8, p. 2474 - 2479
反应条件
1: NaH / dimethylsulfoxide
2: LiAlH4 / diethyl ether
3: H2 / Lindlar catalyst / methanol
View Scheme
参考文献
Kovaleva,A.S. et al.
Journal of Organic Chemistry USSR (English Translation), 1972 , vol. 8, p. 2523 - 2527
Zhurnal Organicheskoi Khimii, 1972 , vol. 8, p. 2474 - 2479
反应条件
1: 89 percent / NH2 / tetrahydrofuran; dimethylsulfoxide
2: 1) 9-BBN, 2) H2O2, AcONa
3: 85 percent / H2 / Ni-P2
View Scheme
参考文献
Ishmuratov; Ishmuratova; Odinokov; Tolstikov
Chemistry of Natural Compounds, 1997 , vol. 33, # 1 p. 25 - 30
反应条件
sodium dithionite; triisooctyl amine; sodium hydrogencarbonate in cyclohexane; water
2 h; Heating; Yield given;
参考文献
Julia, Marc; Stacino, Jean-Pierre
Tetrahedron, 1986 , vol. 42, # 9 p. 2469 - 2474
反应条件
1: 90 percent / NaI / dimethylformamide / 42 h / 60 °C
3: sodium hydroxide / dioxane / 17 h / Ambient temperature; further solvents were also used
4: Adogen, sodium dithionite, NaHCO3 / cyclohexane; H2O / 2 h / Heating
View Scheme
参考文献
Julia, Marc; Stacino, Jean-Pierre
Tetrahedron, 1986 , vol. 42, # 9 p. 2469 - 2474
反应条件
2: sodium hydroxide / dioxane / 17 h / Ambient temperature; further solvents were also used
3: Adogen, sodium dithionite, NaHCO3 / cyclohexane; H2O / 2 h / Heating
View Scheme
参考文献
Julia, Marc; Stacino, Jean-Pierre
Tetrahedron, 1986 , vol. 42, # 9 p. 2469 - 2474
反应条件
1: sodium hydroxide / dioxane / 17 h / Ambient temperature; further solvents were also used
2: Adogen, sodium dithionite, NaHCO3 / cyclohexane; H2O / 2 h / Heating
View Scheme
参考文献
Julia, Marc; Stacino, Jean-Pierre
Tetrahedron, 1986 , vol. 42, # 9 p. 2469 - 2474
反应条件
1: 1) 9-BBN, 2) H2O2, AcONa
2: 85 percent / H2 / Ni-P2
View Scheme
参考文献
Ishmuratov; Ishmuratova; Odinokov; Tolstikov
Chemistry of Natural Compounds, 1997 , vol. 33, # 1 p. 25 - 30
反应条件
1: 94.7 percent / acetonitrile
2: DMSO, NaH / tetrahydrofuran / 0.5 h
View Scheme
参考文献
Horiike; Tanouchi; Hirano
Agricultural and Biological Chemistry, 1980 , vol. 44, # 2 p. 257 - 261
