二氯双(三邻甲苯膦)合钯(II)合成路线 （共 3 条）
反应条件
sodium hydride in 1-methyl-pyrrolidin-2-one; mineral oil T=90°C; 1 h;
参考文献
IRM LLC; LIU, Xiaodong; LI, Xiaolin; LOREN, Jon; MOLTENI, Valentina; NABAKKA, Juliet; NGUYEN, Bao; PETRASSI, Hank Michael James; YEH, Vince
Patent: WO2013/33116 A1, 2013 ;
Location in patent: Page/Page column 125; 126 ;
反应条件
HCl in ethanol; water; acetone PdCl2 in EtOH reacted with HCl soln. and ligand in acetone, refluxed for2 h; washed (EtOH), dried (air), recrystd. (THF);
参考文献
Shaheen, Farkhanda; Badshah, Amin; Gielen, Marcel; Gieck, Christine; Jamil, Mariyam; de Vos, Dick
Journal of Organometallic Chemistry, 2008 , vol. 693, # 6 p. 1117 - 1126
反应条件
sodium hydroxide in ethanol; toluene N2 atmosphere, addn. of EtOH soln. of NaOH to toluene suspension of Pd complex and phosphane ligand, 90°C (5 h), cooling; filtration, washing (water, EtOH and Et2O), drying (vacuum);
参考文献
Beller, Matthias; Riermeier, Thomas H.
European Journal of Inorganic Chemistry, 1998 , # 1 p. 29 - 35
