三氟乙酸2,2,2-三氟乙酯合成路线 （共 21 条）
反应条件
mit UV-Licht.Irradiation;
参考文献
Haszeldine; Nyman
Journal of the Chemical Society, 1959 , p. 387,395
参考文献
Horner, Leopold; Jordan, Manfred
Phosphorus and Sulfur and the Related Elements, 1980 , vol. 8, p. 235 - 242
反应条件
chlorine T=22.84°C; P=760 Torr; IrradiationSynthetic gas;
参考文献
Blanco; Barnes; Teruel, Mariano A.
Journal of Physical Organic Chemistry, 2010 , vol. 23, # 10 p. 950 - 954
反应条件
(K(1+))2lt;(Ph3P)3(Ph2P)Ru2H4gt;(2-)*2C6H14O3; hydrogen in toluene T=90°C; P=4650.4 Torr; 4 h; Yield given;
参考文献
Goldman, Alan S.; Halpern, Jack
Journal of Organometallic Chemistry, 1990 , vol. 382, # 1-2 p. 237 - 253
反应条件
fluorine; cesium fluoride T=-196 - -100°C; 6 h;
参考文献
Akimura, Takashi; Shibakami, Motonari; Tamura, Masanori; Kurosawa, Shigeru; Sekiya, Akira
Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 8 p. 2454 - 2456
反应条件
1: 1-phenyl-propan-1-one With lithium hexamethyldisilazane in tetrahydrofuran T=0 - 20°C; 0.333333 h; 2: TFETFA in tetrahydrofuran T=20°C; 0.333333 h; 3: With ammonium chloride in tetrahydrofuran; water
参考文献
Journal of Organic Chemistry, , vol. 76, # 10 p. 3676 - 3683
反应条件
fluorine; cesium fluoride T=-196 - -100°C; 6 h;
参考文献
Akimura, Takashi; Shibakami, Motonari; Tamura, Masanori; Kurosawa, Shigeru; Sekiya, Akira
Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 8 p. 2454 - 2456
反应条件
1: adamantan-1-yl-ethan-1-one With lithium hexamethyldisilazane in tetrahydrofuran
T=0 - 20°C; 0.333333 h;
2: TFETFA in tetrahydrofuran
T=20°C; 0.333333 h;
3: With ammonium chloride in tetrahydrofuran; water
参考文献
Riofski, Mark V.; John, Jinu P.; Zheng, Mary M.; Kirshner, Julia; Colby, David A.
Journal of Organic Chemistry, 2011 , vol. 76, # 10 p. 3676 - 3683
反应条件
1: cyclo-octatrienone With lithium hexamethyldisilazane in tetrahydrofuran; hexane
T=-78°C; Metallation; 0.5 h;
2: TFETFA in tetrahydrofuran; hexane
T=-78 - -40°C; Acylation; 0.666667 h;
参考文献
Mueller, Paul; Maitrejean, Esther
Collection of Czechoslovak Chemical Communications, 1999 , vol. 64, # 11 p. 1807 - 1826
反应条件
1: 2,5-dibromo-pyridine With n-butyllithium in hexanes; toluene
T=-78°C; 0.5 h;
2: TFETFA in hexanes; toluene
T=-78°C; 2.25 h;
3: With water; ammonium chloride in hexanes; toluene
参考文献
MERCK FROSST CANADA LTD.
Patent: WO2006/133559 A1, 2006 ;
Location in patent: Page/Page column 38 ;
WO 2006/133559 A1
