1,1,1,4,4,4-六氟-2-丁烯合成路线 （共 12 条）
反应条件
hydrogen fluoride; fluorinated chromia T=350°C; P=760.051 Torr;
参考文献
HONEYWELL INTERNATIONAL INC.
Patent: US2011/237844 A1, 2011 ;
Location in patent: Page/Page column 4 ;
反应条件
potassium hydroxide; tetra(n-butyl)ammonium hydroxide in water; tert-butyl alcohol T=4.6 - 68.8°C; 4.36667 h;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: US2010/174123 A1, 2010 ;
Location in patent: Page/Page column 5 ;
反应条件
hydrogen fluoride; chlorine; antimony(V) pentachloride T=78 - 91°C; P=5155.93 - 6707.41 Torr; 71 h; Industry scale;
参考文献
HONEYWELL INTERNATIONAL INC.
Patent: US2011/237843 A1, 2011 ;
Location in patent: Page/Page column 6 ;
反应条件
hydrogen fluoride; chlorine; antimony(V) pentachloride T=78 - 91°C; P=5155.93 - 6707.41 Torr; 71 h; Industry scale;
参考文献
HONEYWELL INTERNATIONAL INC.
Patent: US2011/237844 A1, 2011 ;
Location in patent: Page/Page column 4 ;
反应条件
tritium; quinoline; Lindlar's catalyst P=150 - 500 Torr; 4 h; Ambient temperature;
参考文献
Angelini, G.; Lilla, G.; Sparapani, C.; Ursini, O.; Rossi, E.; et al.
Canadian Journal of Chemistry, 1992 , vol. 70, # 4 p. 1221 - 1228
反应条件
hydrogen; silica gel; nickel T=449.9°C; P=1 Torr; Product distribution;
参考文献
Tomioka, Satoshi; Mori, Tohru; Ueda, Wataru; Morikawa, Yutaka; Ikawa, Tsuneo
Chemistry Letters, 1991 , # 10 p. 1825 - 1826
反应条件
deuterium; quinoline; Lindlar's catalyst in gas P=300 Torr; 4 h; Ambient temperatureother equivalents; other pressure; other reaction time; other H-isotope; Product distribution;
参考文献
Angelini, G.; Lilla, G.; Sparapani, C.; Ursini, O.; Rossi, E.; et al.
Canadian Journal of Chemistry, 1992 , vol. 70, # 4 p. 1221 - 1228
反应条件
sulfur(IV) fluoride T=130°C; 8 h; autoclave; Further byproducts given. Title compound not separated from byproducts;
参考文献
Burmakov, A. I.; Motnyak, L. A.; Kunshenko, B. V.; Alekseeva, L. A.; Yagupol'skii, L. M.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 7 p. 1204 - 1209
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 7 p. 1401 - 1408
反应条件
T=1143.9°C; gas-phase reaction, thermal and thermooxidative stability, various degree of adiabatic compression or various maximum temperature in adiabatic compression pulse, oxygen presence or absence; Product distributionMechanismKinetics;
参考文献
Buravtsev, N. N.; Grigor'ev, A. S.; Kolbanovskii, Yu. A.; Ovsyannikov, A. A.
Russian Journal of Organic Chemistry, 1994 , vol. 30, # 12 p. 1880 - 1890
Zhurnal Organicheskoi Khimii, 1994 , vol. 30, # 12 p. 1794 - 1801
反应条件
T=1006.9°C; gas-phase reaction, thermal and thermooxidative stability, various degree of adiabatic compression or various maximum temperature in adiabatic compression pulse, oxygen presence or absence; Product distributionMechanismKinetics;
参考文献
Buravtsev, N. N.; Grigor'ev, A. S.; Kolbanovskii, Yu. A.; Ovsyannikov, A. A.
Russian Journal of Organic Chemistry, 1994 , vol. 30, # 12 p. 1880 - 1890
Zhurnal Organicheskoi Khimii, 1994 , vol. 30, # 12 p. 1794 - 1801
