palladium diacetate; di-(1-adamantyl)-n-butylphosphine in 1,4-dioxane T=100°C; 20 h;

sodium hydroxide in petroleumether

sulfuric acid; acetic acid in petroleumether; water

ammonia; sodium; iron(III) chloride in petroleumether; diethyl ether

1: thien-2-yl bromide; carbon monoxide; (4-vinylphenyl) boronic acid With N,N,N',N,-tetramethylethylenediamine; palladium diacetate; di-(1-adamantyl)-n-butylphosphine in toluene T=80°C; Suzuki carbonylation; P=1875.19 Torr; 24 h; Inert atmosphere; 2: carbon monoxide With hydrogenchloride; water in 1,4-dioxane; toluene T=100°C; P=30003 Torr; 20 h; Inert atmosphere;

暂无反应条件数据

bis-triphenylphosphine-palladium(II) chloride; carbon monoxide

1: potassium phosphate; palladium diacetate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene / tetrahydrofuran; toluene / 18 h / 100 °C / |Inert atmosphere; |Glovebox; |Sealed tube 2: p-toluidine; sodium sulfate; copper diacetate; potassium phosphate; oxygen / dimethyl sulfoxide / 3 h / 140 °C / |Sealed tube 3: palladium diacetate; di-(1-adamantyl)-n-butylphosphine / 1,4-dioxane / 20 h / 100 °C View Scheme

Yield given. Multistep reaction;

phosphate buffer in water T=20°C; Irradiationalso in the presence of β-cyclodextrin, var. temp.; Quantum yieldRate constantMechanism;