2,6-二氯吡啶-4-硼酸频哪醇酯合成路线 （共 6 条）
反应条件
1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); 4,4'-di-tert-butyl-2,2'-dipyridyl in tert-butyl methyl ether Inert atmosphere; 2: 2,6-Dichloropyridine in tert-butyl methyl ether T=80°C; 0.05 h; Inert atmosphereMicrowave irradiation;
参考文献
Harrisson, Peter; Morris, James; Marder, Todd B.; Steel, Patrick G.
Organic Letters, 2009 , vol. 11, # 16 p. 3586 - 3589
反应条件
1,10-phenanthroline; chloro-1,5-cyclooctadiene iridium(I) dimer in 1,2-dichloro-ethane T=100°C; 15 h;
参考文献
MERCK SHARP and DOHME LIMITED
Patent: WO2004/74290 A1, 2004 ;
Location in patent: Page 38 ;
WO 2004/074290 A1
反应条件
(.eta.(5)-indenyl)Ir(1,5-cyclooctadiene); 1,2-bis(dimethylphosphine)ethane in cyclohexane T=150°C; 3 h;
参考文献
Board of Trustees of Michigan State University
Patent: US2004/30197 A1, 2004 ;
Location in patent: Page 14; 17 ;
反应条件
Cu(NO3)2*3H2O; cesium fluoride in methanol; water T=100°C; 3 h;
参考文献
Liskey, Carl W.; Liao, Xuebin; Hartwig, John F.
Journal of the American Chemical Society, 2010 , vol. 132, # 33 p. 11389 - 11391
反应条件
Oxonereg; in acetone T=25°C; 0.116667 h;
参考文献
Norberg, A. Monica; Smith III, Milton R.; Maleczka Jr., Robert E.
Synthesis, 2011 , # 6 art. no. M08010SS, p. 857 - 859
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium hydroxide in tert-butyl methyl ether; water
T=80°C; Suzuki-Miyaura coupling; 3 h;
参考文献
Harrisson, Peter; Morris, James; Steel, Patrick G.; Marder, Todd B.
Synlett, 2009 , # 1 p. 147 - 150
