4-甲基-3-硝基苯甲醇合成路线 （共 11 条）
反应条件
sodium tetrahydroborate; water in 1,4-dioxane Cooling with iceReflux;
参考文献
Bayer CorpScience AG
Patent: US2010/179194 A1, 2010 ;
Location in patent: Page/Page column 25 ;
反应条件
potassium hydroxide; ethanol
参考文献
Auwers
Justus Liebigs Annalen der Chemie, 1906 , vol. 344, p. 179
反应条件
(i) (nitration), (ii) NaBH4; Multistep reaction;
参考文献
Fuchs,R.; Carlton,D.M.
Journal of Organic Chemistry, 1962 , vol. 27, p. 1520 - 1523
反应条件
manganese(IV) oxide in dichloromethane 336 h; Ambient temperature;
参考文献
Somei, Masanori
Chemical and Pharmaceutical Bulletin, 1986 , vol. 34, # 10 p. 4109 - 4115
反应条件
TiCl3 in tetrahydrofuran; water 0.116667 h; Ambient temperature;
参考文献
Somei, Masanori
Chemical and Pharmaceutical Bulletin, 1986 , vol. 34, # 10 p. 4109 - 4115
参考文献
Fuchs,R.; Carlton,D.M.
Journal of Organic Chemistry, 1962 , vol. 27, p. 1520 - 1523
反应条件
1: 78.3 percent / MnO2 / CH2Cl2 / 336 h / Ambient temperature 2: dimethylformamide / 13.5 h / Heating 3: titanium(III) chloride / tetrahydrofuran; pyridine / 0.33 h / 7 °C View Scheme
参考文献
Somei, Masanori
Chemical and Pharmaceutical Bulletin, 1986 , vol. 34, # 10 p. 4109 - 4115
反应条件
1: 78.3 percent / MnO2 / CH2Cl2 / 336 h / Ambient temperature 2: dimethylformamide / 13.5 h / Heating 3: titanium(III) chloride / tetrahydrofuran; pyridine / 0.33 h / 7 °C View Scheme
参考文献
Somei, Masanori
Chemical and Pharmaceutical Bulletin, 1986 , vol. 34, # 10 p. 4109 - 4115
反应条件
phosphorus tribromide in benzene
参考文献
Prasad,R.; Bhaduri,A.P.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1979 , vol. 18, p. 443 - 448
反应条件
1: PBr3 / benzene
2: benzene
View Scheme
参考文献
Prasad,R.; Bhaduri,A.P.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1979 , vol. 18, p. 443 - 448
