2-[(Z)-2-戊烯基]环戊烯-1-酮合成路线 （共 38 条）
反应条件
1: (i) Mg, Et2O, (ii) /BRN= 741856/, benzene-1,4-diol
2: CrO3, aq. H2SO4 / diethyl ether / -20 - -15 °C
3: NaOMe / methanol
4: (i) aq. NaOH, THF, (ii) aq. H2SO4
5: aq. NaOH / diethyl ether / Ambient temperature
View Scheme
参考文献
Dubs; Stussi
Helvetica Chimica Acta, 1978 , vol. 61, # 3 p. 990 - 997
反应条件
1: CrO3, aq. H2SO4 / diethyl ether / -20 - -15 °C
2: NaOMe / methanol
3: (i) aq. NaOH, THF, (ii) aq. H2SO4
4: aq. NaOH / diethyl ether / Ambient temperature
View Scheme
参考文献
Dubs; Stussi
Helvetica Chimica Acta, 1978 , vol. 61, # 3 p. 990 - 997
反应条件
1: NaOMe / methanol
2: (i) aq. NaOH, THF, (ii) aq. H2SO4
3: aq. NaOH / diethyl ether / Ambient temperature
View Scheme
参考文献
Dubs; Stussi
Helvetica Chimica Acta, 1978 , vol. 61, # 3 p. 990 - 997
反应条件
1: (i) aq. NaOH, THF, (ii) aq. H2SO4
2: aq. NaOH / diethyl ether / Ambient temperature
View Scheme
参考文献
Dubs; Stussi
Helvetica Chimica Acta, 1978 , vol. 61, # 3 p. 990 - 997
参考文献
Meyers,A.I.; Nazarenko,N.
Journal of Organic Chemistry, 1973 , vol. 38, p. 175 - 176
反应条件
in cyclohexane
Ambient temperatureIrradiation; Further byproducts given. Title compound not separated from byproducts;
参考文献
Rudolph, Andreas; Weedon, Alan C.
Canadian Journal of Chemistry, 1990 , vol. 68, # 9 p. 1590 - 1597
反应条件
1: (i) H2, Lindlar catalyst, (ii) (acid hydrolysis), (iii) DCC, CuCl, Et2O
2: 240 °C
View Scheme
参考文献
Bahurel,Y. et al.
Synthesis, 1974 , p. 118 - 119
反应条件
sodium methylate in methanol
T=0°C; 10 h; Yield given;
参考文献
Kataoka, Hideaki; Yamada, Toshiro; Goto, Kuniaki; Tsuji, Jiro
Tetrahedron, 1987 , vol. 43, # 18 p. 4107 - 4112
