2,2'-azobisisobutyronitrile in neat (no solvent) standard Schlenk technique; flask with 2,2'-azobisisobutyronitrile and CH2CHSnBu3 was cooled to -78°C and evacuated; GeCl4 was added; mixt. was heated at 90°C for 3 h; distd. (vac.);

(E)-vinyl chloride in neat (no solvent) 600-700°C, in presence of HSiCl3;

(E)-vinyl chloride in neat (no solvent) thermolysis;

(E)-vinyl chloride in neat (no solvent) thermolysis;

(E)-vinyl chloride in neat (no solvent) thermolysis;

(E)-vinyl chloride in neat (no solvent) thermolysis;

(E)-vinyl chloride in neat (no solvent) thermolysis;

methyl-magnesium iodide; aluminium trichloride; trichlorophosphate in diethyl ether CH2CHGeCl3 added dropwise to adamantane and AlCl3 (stirring); heated (140°C, 2 h, stirring); cooled; hexane and POCl3 added; ether added; MeMgI added dropwise; boiled (5 h); colled; fractionated; GLC; elem.anal.;