in diethyl ether; cyclohexane Kinetics; Bu3SnH (2 mmol) in ether placed in Schlenk tube and cooled to 0°C under Ar, LDA (1 mmol, 1.6 M soln. in cyclohexane) added, samples removed periodically, quenched with water; analyzed by GC;
参考文献
Reimann, Werner; Kuivila, Henry G.; Farah, Dan; Apoussidis, Theodorus
Organometallics, 1987 , vol. 6, p. 557 - 565
in diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;
1: para-chloro-benzonitrile; tri-isopropoxy-borane; lithium diisopropyl amide 2: 3-hydroxy-2,2-dimethylpropanol Title compound not separated from byproducts;
参考文献
Lysen, Morten; Hansen, Henriette M.; Begtrup, Mikael; Kristensen, Jesper L.
Journal of Organic Chemistry, 2006 , vol. 71, # 6 p. 2518 - 2520
