Hirsutenone; (4E)-1,7-双(3,4-二羟基苯基)-4-庚烯-3-酮合成路线 （共 6 条）
反应条件
1: 80 percent / H2 / Pd/C / ethyl acetate / 2 h / 20 °C
2: 33 percent / NaBH4 / methanol / 2 h / 20 °C
3: 84 percent / p-TsOH / benzene / 2 h / Heating
4: 36 percent / AlCl3; pyridine / 1,2-dichloro-ethane / 4 h / Heating
View Scheme
参考文献
Venkateswarlu; Ramachandra; Rambabu; Subbaraju
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2001 , vol. 40, # 6 p. 495 - 497
反应条件
1: 84 percent / p-TsOH / benzene / 2 h / Heating
2: 36 percent / AlCl3; pyridine / 1,2-dichloro-ethane / 4 h / Heating
View Scheme
参考文献
Venkateswarlu; Ramachandra; Rambabu; Subbaraju
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2001 , vol. 40, # 6 p. 495 - 497
反应条件
1: 33 percent / NaBH4 / methanol / 2 h / 20 °C
2: 84 percent / p-TsOH / benzene / 2 h / Heating
3: 36 percent / AlCl3; pyridine / 1,2-dichloro-ethane / 4 h / Heating
View Scheme
参考文献
Venkateswarlu; Ramachandra; Rambabu; Subbaraju
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2001 , vol. 40, # 6 p. 495 - 497
反应条件
sulfuric acid; water
T=50°C; 3 h;
参考文献
Park, Daae; Kim, Hyoung Ja; Jung, Seo Yun; Yook, Chang-Soo; Jin, Changbae; Lee, Yong Sup
Chemical and Pharmaceutical Bulletin, 2010 , vol. 58, # 2 p. 238 - 241
反应条件
hydrogenchloride
1 h;
参考文献
Kuroyanagi, Masanori; Shimomae, Mari; Nagashima, Yasuo; Muto, Norio; Okuda, Takuro; Kawahara, Nobuo; Nakane, Takahisa; Sano, Toshikazu
Chemical and Pharmaceutical Bulletin, 2005 , vol. 53, # 12 p. 1519 - 1523
反应条件
hydrogenchloride
1 h;
参考文献
Kuroyanagi, Masanori; Shimomae, Mari; Nagashima, Yasuo; Muto, Norio; Okuda, Takuro; Kawahara, Nobuo; Nakane, Takahisa; Sano, Toshikazu
Chemical and Pharmaceutical Bulletin, 2005 , vol. 53, # 12 p. 1519 - 1523
