1-甲基-3-亚甲基环戊烷e合成路线 （共 11 条）
反应条件
carbon monoxide; palladium diacetate; 1,4-di(diphenylphosphino)-butane in ethylene glycol dimethyl ether T=150°C; P=5168 Torr; 16 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Ali, Bassam El; Alper, Howard
Journal of Organic Chemistry, 1993 , vol. 58, # 13 p. 3595 - 3596
反应条件
1: Methyltriphenylphosphonium bromide With n-butyllithium in tetrahydrofuran; hexane
T=-50°C; 0.333333 h; Inert atmosphere;
2: 2-methyl-cyclopentanone in tetrahydrofuran; hexane
T=20 - 60°C; 5 h; Inert atmosphere;
参考文献
Zou, Yuanlin; Wang, Dongren; Wurst, Klaus; Kuehnel, Christa; Reinhardt, Ingrid; Decker, Ulrich; Gurram, Venkatanavarana; Camadanli, Sebnem; Buchmeiser, Michael R.
Chemistry - A European Journal, 2011 , vol. 17, # 49 p. 13832 - 13846
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
T=80°C; various concentration of tributylstannane, Eact(excit.); MechanismProduct distribution;
参考文献
Beckwith, Athelstan L.J.; O'Shea, Dennis M.
Tetrahedron Letters, 1986 , vol. 27, # 38 p. 4525 - 4528
反应条件
in benzene-d6
addn. 6-hepten-2-one to suspn. W-complex/C6D6, amber soln. stirred at ambient temp. for 0.5h, heated to 85°C for 15 min; volatiles transfered in vac.;
参考文献
Bryan, Jeffrey C.; Arterburn, Jeffrey B.; Cook, Gerald K.; Mayer, James M.
Organometallics, 1992 , vol. 11, p. 3965 - 3970
反应条件
diethyl aluminium hydride in hexane
1) 0 deg C, 30 min, 2) reflux overnight;
参考文献
Smith, Michael J.; Wilson, Stanley E.
Tetrahedron Letters, 1982 , vol. 23, # 48 p. 5013 - 5016
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
T=80°C; various concentration of tributylstannane; MechanismProduct distribution;
参考文献
Beckwith, Athelstan L.J.; O'Shea, Dennis M.
Tetrahedron Letters, 1986 , vol. 27, # 38 p. 4525 - 4528
参考文献
Brown, Herbert C.; Ford, Thomas M.
Journal of Organic Chemistry, 1981 , vol. 46, # 3 p. 647 - 648
反应条件
in benzene-d6
react. W-complex with 6-hepten-2-one at 25°C;
参考文献
Bryan, Jeffrey C.; Arterburn, Jeffrey B.; Cook, Gerald K.; Mayer, James M.
Organometallics, 1992 , vol. 11, p. 3965 - 3970
反应条件
thiophenol in tetrahydrofuran
T=48°C; KineticsProduct distribution; Further Variations:TemperaturesReagents;
参考文献
Kantorowski, Eric J.; Le, Daniel D.; Hunt, Caleb J.; Barry-Holson, Keegan Q.; Lee, Jessica P.; Ross, Lauren N.
Journal of Organic Chemistry, 2008 , vol. 73, # 4 p. 1593 - 1596
参考文献
Froemsdorf et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 643,646
