7-甲基-3,4-二氢-2H-苯并[b]氧杂环庚三烯-5-酮合成路线 （共 13 条）
反应条件
1: 73 percent / 4percent ethanolic KOH 2: 2 N NaOH, 30percent H2O2 / ethanol / Heating 3: 53 percent / gl. acetic acid, H2N-NH2 / ethanol / Heating View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 28, # 1-11 p. 37 - 41
参考文献
Tripathi, Ravish C.; Tandon, V. K.; Khanna, J. M.; Saxena, Anil K.; Anand, Nitya
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 37 - 41
反应条件
1: 70 percent / 4percent ethanolic KOH 2: 2 N NaOH, 30percent H2O2 / ethanol / 1) 100 deg C, 20 min, 2) 30 deg C, 18 h 3: 50 percent / gl. acetic acid, NH2-NH2 / ethanol / Heating View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 28, # 1-11 p. 37 - 41
反应条件
1: 70 percent / 4percent ethanolic KOH 2: 2 N NaOH, 30percent H2O2 / ethanol / 1) 100 deg C, 20 min, 2) 30 deg C, 18 h 3: 47.5 percent / gl. acetic acid / ethanol / 12 h / 90 °C View Scheme
参考文献
Tripathi, Ravish C.; Tandon, V. K.; Khanna, J. M.; Saxena, Anil K.; Anand, Nitya
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 37 - 41
反应条件
1: 73 percent / 4percent ethanolic KOH 2: 2 N NaOH, 30percent H2O2 / ethanol / Heating 3: 56 percent / gl. acetic acid / ethanol / Heating View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 28, # 1-11 p. 37 - 41
反应条件
1: 73 percent / 4percent ethanolic KOH 2: 2 N NaOH, 30percent H2O2 / ethanol / Heating 3: 51 percent / gl. acetic acid / ethanol / Heating View Scheme
参考文献
Tripathi, Ravish C.; Tandon, V. K.; Khanna, J. M.; Saxena, Anil K.; Anand, Nitya
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 37 - 41
反应条件
1: Jone's reagent / acetone / 1 h / 0 °C
2: trifluoroacetic acid / dichloromethane / 0 - 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Yajun; Park, Se Kyung; Xiao, Yan; Chae, Junghyun
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 26 p. 4747 - 4753
反应条件
1: copper dichloride; caesium carbonate / 20 h / 130 °C / |Inert atmosphere; |Schlenk technique
2: Jone's reagent / acetone / 1 h / 0 °C
3: trifluoroacetic acid / dichloromethane / 0 - 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Yajun; Park, Se Kyung; Xiao, Yan; Chae, Junghyun
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 26 p. 4747 - 4753
反应条件
1: copper dichloride; caesium carbonate / 20 h / 130 °C / |Inert atmosphere; |Schlenk technique
2: Jone's reagent / acetone / 1 h / 0 °C
3: trifluoroacetic acid / dichloromethane / 0 - 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Yajun; Park, Se Kyung; Xiao, Yan; Chae, Junghyun
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 26 p. 4747 - 4753
反应条件
aluminium trichloride in carbon disulfide
3 h; Heating; Yield given;
参考文献
Tandon; Khanna; Chandra; Anand
Tetrahedron, 1990 , vol. 46, # 8 p. 2871 - 2882
