in anhydrous butyl ether Addn. of organomagnesium soln. to metal salt.; GC after 2-5h.;
参考文献
Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk), , vol. 286 - 288, p. 10 - 12
Doklady Akademii Nauk SSSR, , vol. 286, p. 132 - 134
in anhydrous butyl ether; benzene Addn. of organomagnesium soln. to metal salt soln. in benzene.; GC after 2-5h.;
参考文献
Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk), , vol. 286 - 288, p. 10 - 12
Doklady Akademii Nauk SSSR, , vol. 286, p. 132 - 134
in anhydrous butyl ether Addn. of organomagnesium soln. to metal salt.; GC after 2-5h.;
参考文献
Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk), , vol. 286 - 288, p. 10 - 12
Doklady Akademii Nauk SSSR, , vol. 286, p. 132 - 134
1: With tetrakis(triphenylphosphine) palladium(0); copper(l) chloride in tetrahydrofuran; diethyl ether T=0°C; 2: With pyridine; pyridinium poly(hydrogen fluoride) in ethyl acetate
参考文献
Angewandte Chemie - International Edition, , vol. 49, # 31 p. 5375 - 5377
in diethyl ether inert atmosphere; addn. of 2 equiv. CD3MgI to Zr-complex, then addn. of 1 equiv. MeMgBr, standing for 60 min at 20°C; product mixt. not isolated, reaction followed by (1)H-NMR spectroscopy;
1: bromobenzene-d5 With iodine; magnesium in diethyl ether
T=10°C; Grignard reaction; 3 h;
2: With tetrachlorosilane in diethyl ether
T=0 - 20°C; 2 h;
3: CD3MgI in tetrahydrofuran; diethyl ether
T=20°C; 2 h; Title compound not separated from byproducts;
参考文献
Buswell, Marina; Fleming, Ian; Ghosh, Usha; Mack, Stephen; Russell, Matthew; Clark, Barry P.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 20 p. 3006 - 3017
