2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride; magnesium iodide in toluene Heatingchemo- and regioselective reductive opening of several epoxides with various reaction conditions; MechanismProduct distribution;
ammonia; hydrogen; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; 2,2'-bis[[bis(3-sulfophenyl)phosphino]methyl]-4,4',7,7'-tetrasulfo-1,1'-binaphthyl octasodium salt in n-heptane; water T=130°C; P=66756.7 Torr; 7 h; Product distribution / selectivity;
参考文献
Degussa AG
Patent: US6884887 B1, 2005 ;
Location in patent: Page/Page column 9-10 ;
sulfuric acid; nickel in methanol; water T=30°C; 2 h;
参考文献
Okimoto, Mitsuhiro; Takahashi, Yukio; Nagata, Yuji; Satoh, Masanori; Sueda, Satoru; Yamashina, Tsunaki
Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 7 p. 1405 - 1406