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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
41446-54-2
合成路线
(共 13 条)
35329-42-1
1-十一烯-3-醇
+
925-90-6
乙基溴化镁
→
反应条件
41446-54-2
+
41446-55-3
反应条件
titanium(IV) isopropylate in diethyl ether T=20°C; Title compound not separated from byproducts;
参考文献
Kulinkovich; Epstein; Isakov; Khmel'nitskaya
Synlett, 2001 , # 1 p. 49 - 52
925-90-6
乙基溴化镁
+
109929-20-6
→
反应条件
41446-54-2
+
41446-55-3
反应条件
titanium(IV) isopropylate in diethyl ether T=20°C; Title compound not separated from byproducts;
参考文献
Kulinkovich; Epstein; Isakov; Khmel'nitskaya
Synlett, 2001 , # 1 p. 49 - 52
56956-46-8
+
97-93-8
三乙铝
→
反应条件
41446-54-2
反应条件
1: With zirconocene dichloride in hexane T=0 - 20°C; 4 h; 2: With hydrogenchloride in hexane; water
参考文献
Khafizova; Ibragimov; Gil'fanova; Khalilov; Dzhemilev
Russian Chemical Bulletin, 2001 , vol. 50, # 11 p. 2188 - 2192
694-54-2
四氢-2H-吡喃-2-醇
→
反应条件
41446-54-2
+
2801-82-3
反应条件
2.1: dipyridinium dichromate / dichloromethane / 3 h / Molecular sieve 3.1: magnesium / diethyl ether 3.2: Cooling with ice; Reflux 4.1: pyridine / dichloromethane / 20 °C / Inert atmosphere 5.1: 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride / hexane / 25 °C / Cooling with liquid nitrogen; Sealed tube; UV-irradiation View Scheme
参考文献
Beckwith, Athelstan L. J.; Schiesser, Carl H.
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 6 p. 1736 - 1743
1292288-89-1
→
反应条件
41446-54-2
+
2801-82-3
反应条件
1: pyridine / dichloromethane / 20 °C / Inert atmosphere 2: 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride / hexane / 25 °C / Cooling with liquid nitrogen; Sealed tube; UV-irradiation View Scheme
参考文献
Beckwith, Athelstan L. J.; Schiesser, Carl H.
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 6 p. 1736 - 1743
64275-75-8
→
反应条件
41446-54-2
+
2801-82-3
反应条件
1.1: dipyridinium dichromate / dichloromethane / 3 h / Molecular sieve 2.1: magnesium / diethyl ether 2.2: Cooling with ice; Reflux 3.1: pyridine / dichloromethane / 20 °C / Inert atmosphere 4.1: 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride / hexane / 25 °C / Cooling with liquid nitrogen; Sealed tube; UV-irradiation View Scheme
参考文献
Beckwith, Athelstan L. J.; Schiesser, Carl H.
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 6 p. 1736 - 1743
2277-17-0
→
反应条件
41446-54-2
+
2801-82-3
反应条件
1.1: magnesium / diethyl ether 1.2: Cooling with ice; Reflux 2.1: pyridine / dichloromethane / 20 °C / Inert atmosphere 3.1: 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride / hexane / 25 °C / Cooling with liquid nitrogen; Sealed tube; UV-irradiation View Scheme
参考文献
Beckwith, Athelstan L. J.; Schiesser, Carl H.
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 6 p. 1736 - 1743
124-19-6
壬醛
+
1779-51-7
丁基三苯基溴化膦
→
反应条件
41446-54-2
+
41446-55-3
反应条件
potassium carbonate in 1,4-dioxane; water 3.5 h; Heating; Yield given. Yields of byproduct given;
参考文献
Le Bigot, Y.; Delmas, M.; Gaset, A.
Synthetic Communications, 1982 , vol. 12, # 2 p. 107 - 112
546-67-8
乙酸铅(IV)
+
544-63-8
肉豆蔻酸
+
71-43-2
苯
→
反应条件
41015-28-5
+
60826-31-5
+
629-50-5
十三烷
+
2437-56-1
1-十三烯
+
1072-33-9
乙酸十三酯
+
6508-77-6
+
6434-76-0
+
25524-42-9
+
23051-84-5
+
41446-54-2
+
41446-55-3
+
41446-53-1
+
41446-57-5
+
41446-59-7
+
41446-58-6
+
123-02-4
十三烷基苯
+
60826-27-9
+
60826-29-1
+
60826-30-4
反应条件
T=81°C;
参考文献
Teodorovic, Aleksandar V.; Badjuk, Dalibor M.; Stevanovic, Nenad; Pavlovic, Radoslav Z.
Journal of Molecular Structure, 2013 , vol. 1040, p. 19 - 24
1292288-90-4
→
反应条件
41446-54-2
+
2801-82-3
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in hexane T=25°C; Cooling with liquid nitrogenSealed tubeUV-irradiation; Kinetics; TemperatureConcentrationSolvent; stereoselective reaction;
参考文献
Beckwith, Athelstan L. J.; Schiesser, Carl H.
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 6 p. 1736 - 1743
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