2,3,7,8,12,13,17,18-辛乙基-21H,23H-卟吩钌(II)羰基合成路线 （共 4 条）
反应条件
in dichloromethane
complex dissociates in CH2Cl2;
参考文献
Levine, Leanna M. A.; Holten, Dewey
Journal of Physical Chemistry, 1988 , vol. 92, # 3 p. 714 - 720
反应条件
carbon monoxide in dichloromethane
CH2Cl2 soln. of the Ru complex subjected to 1 atm CO; Ru(OEP)(PhNO)(CO) detected in situ at lower temps. (<-40°C);
参考文献
Crotti, Corrado; Sishta, Chand; Pacheco, Andrew; James, Brian R.
Inorganica Chimica Acta, 1988 , vol. 141, p. 13 - 16
反应条件
in benzene
byproducts: Ru2(N4C20H4(C2H5)8)2; under inert atm., addn. of excess of piperidine to complex soln. at room temp., further unidentified product; monitored by 1H-NMR and UV-VIS;
参考文献
Seyler, Jeffery W.; Fanwick, Phillip E.; Leidner, Charles R.
Inorganic Chemistry, 1992 , vol. 31, p. 3699 - 3700
反应条件
in toluene
dissolving Ru3(CO)12 and porphyrin in toluene; refluxing for 48 h in air; modified method of M. Tsutsui, D. Oestfeld and J. N. Frances, J. Coord. Chem., 1971, 1, 115;; evapn. of solvent; chromy. on silica gel with CHCl3/hexane; collecting second red fraction; evapn. of solvent; 2 fold recrystn. from THF/hexane;;
参考文献
Kadish, Karl M.; Hu, Yu; Tagliatesta, Pietro; Boschi, Tristano
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1993 , # 8 p. 1167 - 1172
