1: 50 percent / mercuric acetate / 10 h / Heating
2: 0.5 h / 185 - 190 °C
3: 70 percent / 1.) r. t. overnight 2.) 3 h 50 deg C
4: 74 percent / PTS / benzene / 6 h / Heating
5: H2O / PTS / acetone / 24 h / Ambient temperature
6: 79 percent / diethyl ether / 1.) 8 h 2.) reflux 2 h
View Scheme
参考文献
Vig, O. P.; Sharma, M. L.; Trehan, Navneet; Verma, N. K.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1980 , vol. 19, # 6 p. 450 - 452
Kocienski, Philip; Todd, Michael
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1783 - 1789
1: 92 percent / chlorodimethylformiminium chloride / dimethylformamide / 0.5 h / 0 °C
2: 85 percent / 1,2M-NaOEt / ethanol / 2 h / Ambient temperature
View Scheme
参考文献
Kocienski, Philip; Todd, Michael
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1783 - 1789
N-(chloromethylene)-N-methylmethanaminium chloride in N,N-dimethyl-formamide
T=0°C; 0.5 h;
参考文献
Kocienski, Philip; Todd, Michael
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1783 - 1789
1: 81 percent / Hg(II)
2: 92 percent / 1.33 h / 180 - 185 °C / base-washed flask
3: 92 percent / LiAlH4
4: pyridine / 5 h / 0 °C
5: 5.805 g / 1.1M ethanolic NaOEt / 1 h / Heating
View Scheme
参考文献
Kocienski, Philip; Todd, Michael
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1783 - 1789
1: 81 percent / Hg(II)
2: 92 percent / 1.33 h / 180 - 185 °C / base-washed flask
3: 92 percent / LiAlH4
4: pyridine / 5 h / 0 °C
5: 5.805 g / 1.1M ethanolic NaOEt / 1 h / Heating
6: 83 percent / bis(trimethylsilyl) peroxide / benzene / 24 h / Heating
View Scheme
参考文献
Kocienski, Philip; Todd, Michael
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1783 - 1789
