1: With trimethylsilyl trifluoromethanesulfonate; benzo[1,3,2]dioxaborole; [Rh(acac)(COD)]2; (R)-1-(2-phenylquinazolin-4-yl)-2-(Ph2P)-naphthalene in tetrahydrofuran T=0°C; Addition; Hydroboration; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran T=20°C; Oxidation; Hydrolysis; 1 h; Further stages. Title compound not separated from byproducts.;
参考文献
Maxwell, Aoife C.; Flanagan, Susan P.; Goddard, Richard; Guiry, Patrick J.
Tetrahedron Asymmetry, 2010 , vol. 21, # 11-12 p. 1458 - 1473
Winstein; Trifan
Journal of the American Chemical Society, 1952 , vol. 74, p. 1154,1159
Journal of the American Chemical Society, 1949 , vol. 71, p. 2953
1: With CF3O3S(1-)*C45H39N2OPRh(1+); benzo[1,3,2]dioxaborole in tetrahydrofuran T=0°C; Inert atmosphere; 2: With dihydrogen peroxide; sodium hydroxide in ethanol; water T=0 - 20°C; optical yield given as percent eeenantioselective reaction;
参考文献
Maxwell, Aoife C.; Flanagan, Susan P.; Goddard, Richard; Guiry, Patrick J.
Tetrahedron Asymmetry, 2010 , vol. 21, # 11-12 p. 1458 - 1473
