7,7-二甲基双环2.2.1庚烷-2,3-二酮合成路线 （共 9 条）
反应条件
1: pyridine / 24 h / Heating
2: aq. NaHCO3 / pyridine
3: 60 percent / O3 / methanol / -80 - -70 °C
4: 90 percent / selenium dioxide / acetic acid / 15 h / 140 °C
View Scheme
参考文献
Cervantes, Humberto; Khac, Duc Do; Fetizon, Marcel; Guir, Frederic; Beloeil, Jean-Claude; Lallemand, Jean-Yves
Tetrahedron, 1986 , vol. 42, # 13 p. 3491 - 3502
反应条件
1: 60 percent / O3 / methanol / -80 - -70 °C
2: 90 percent / selenium dioxide / acetic acid / 15 h / 140 °C
View Scheme
参考文献
Cervantes, Humberto; Khac, Duc Do; Fetizon, Marcel; Guir, Frederic; Beloeil, Jean-Claude; Lallemand, Jean-Yves
Tetrahedron, 1986 , vol. 42, # 13 p. 3491 - 3502
反应条件
1: aq. NaHCO3 / pyridine
2: 60 percent / O3 / methanol / -80 - -70 °C
3: 90 percent / selenium dioxide / acetic acid / 15 h / 140 °C
View Scheme
参考文献
Cervantes, Humberto; Khac, Duc Do; Fetizon, Marcel; Guir, Frederic; Beloeil, Jean-Claude; Lallemand, Jean-Yves
Tetrahedron, 1986 , vol. 42, # 13 p. 3491 - 3502
反应条件
1: thionyl chloride / 1 h / Heating
2: 1.55 g / bis(triphenylphosphine)tetrahydroboratocopper(I), triphenylphosphine / acetone / 0.5 h / Heating
3: 0.52 g / tris(triphenylphosphine)chlororhodium(I) / 2 h / 180 °C
4: 0.30 g / selenium dioxide / acetic acid / 1 h / Heating
View Scheme
参考文献
Polonski, Tadeusz
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 305 - 310
反应条件
1: 0.52 g / tris(triphenylphosphine)chlororhodium(I) / 2 h / 180 °C
2: 0.30 g / selenium dioxide / acetic acid / 1 h / Heating
View Scheme
参考文献
Polonski, Tadeusz
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 305 - 310
反应条件
1: 1.55 g / bis(triphenylphosphine)tetrahydroboratocopper(I), triphenylphosphine / acetone / 0.5 h / Heating
2: 0.52 g / tris(triphenylphosphine)chlororhodium(I) / 2 h / 180 °C
3: 0.30 g / selenium dioxide / acetic acid / 1 h / Heating
View Scheme
参考文献
Polonski, Tadeusz
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 305 - 310
反应条件
1: HNO3
2: RuO4
3: SeO2
View Scheme
参考文献
Kokke,W.C.M.C.
Journal of Organic Chemistry, 1973 , vol. 38, # 17 p. 2989 - 2994
反应条件
1: RuO4
2: SeO2
View Scheme
参考文献
Kokke,W.C.M.C.
Journal of Organic Chemistry, 1973 , vol. 38, # 17 p. 2989 - 2994
反应条件
in diethyl ether
T=25°C;
参考文献
Cervantes, Humberto; Khac, Duc Do; Fetizon, Marcel; Guir, Frederic; Beloeil, Jean-Claude; Lallemand, Jean-Yves
Tetrahedron, 1986 , vol. 42, # 13 p. 3491 - 3502
