三甲基(对甲苯乙炔)硅烷合成路线 （共 36 条）
反应条件
toluene-4-sulfonic acid in neat (no solvent)
T=60 - 140°C; 14 h; Green chemistry; regioselective reaction;
参考文献
Gao, Qi; Bao, Fang-Ping; Feng, Xiao-Jing; Pan, Ying-Ming; Wang, Heng-Shan; Li, Dian-Peng
Arkivoc, 2013 , vol. 2013, # 3 p. 49 - 60
反应条件
1: potassium fluoride / dimethyl sulfoxide / 16 h / 20 °C
2: potassium hydroxide / dimethyl sulfoxide; water / 1 h / 130 °C / |Microwave irradiation
View Scheme
参考文献
Klukas, Fabian; Grunwald, Alexander; Menschel, Franziska; Mueller, Thomas J. J.
Beilstein Journal of Organic Chemistry, 2014 , vol. 10, p. 672 - 679
反应条件
silver nitrate in tetrahydrofuran; water
T=20°C; 30 h; Inert atmosphere;
参考文献
Deng, Gui Sheng; Sun, Teng Fei
Chinese Chemical Letters, 2012 , vol. 23, # 10 p. 1115 - 1118,4
反应条件
silver nitrate in tetrahydrofuran; water
T=20°C; 24 h; Inert atmosphere;
参考文献
Deng, Gui Sheng; Sun, Teng Fei
Chinese Chemical Letters, 2012 , vol. 23, # 10 p. 1115 - 1118,4
反应条件
tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tetrabutyl ammonium fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene; (Me)CgPPh in tetrahydrofuran; N,N-dimethyl-formamide
T=90°C; microwave-assisted Sonogashira-carbonylation-cyclization reaction; P=760.051 Torr; 0.5 h; Microwave irradiation;
参考文献
Awuah, Emelia; Capretta, Alfredo
Organic Letters, 2009 , vol. 11, # 15 p. 3210 - 3213
反应条件
1.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.33 h / 0 °C / |Inert atmosphere
2.1: n-butyllithium / hexane; tetrahydrofuran / 1.5 h / -78 °C / |Inert atmosphere
2.2: 19 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
O'Rourke, Natasha F.; Wulff, Jeremy E.
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 8 p. 1292 - 1308
