2-乙酰基-4-戊酮酸乙酯合成路线 （共 20 条）
反应条件
potassium hydroxide; N-benzyl-N,N,N-triethylammonium chloride in N,N-dimethyl-formamide T=45°C; 1.5 h; other bases;
参考文献
Sizov, A. Yu.; Yanovskaya, L. A.; Dombrovskii, V. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 2.2 p. 410 - 411
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 2 p. 473 - 474
反应条件
sodium t-butanolate T=60°C; 3 h;
参考文献
Gu, Xue-Ping; Nishida, Nobuyuki; Ikeda, Isao; Okahara, Mitsuo
Journal of Organic Chemistry, 1987 , vol. 52, # 15 p. 3192 - 3196
反应条件
pyridinium p-toluenesulfonate in water; acetonitrile 72 h; Ambient temperature;
参考文献
Antonioletti, Roberto; Bonadies, Francesco; Scettri, Arrigo
Gazzetta Chimica Italiana, 1991 , vol. 121, # 5 p. 233 - 234
反应条件
benzene Unter Kuehlung;
参考文献
Stevenson; Johnson
Journal of the American Chemical Society, 1937 , vol. 59, p. 2525,2529
反应条件
sodium t-butanolate T=60°C; 3 h;
参考文献
Gu, Xue-Ping; Nishida, Nobuyuki; Ikeda, Isao; Okahara, Mitsuo
Journal of Organic Chemistry, 1987 , vol. 52, # 15 p. 3192 - 3196
反应条件
benzophenone in dichloromethane Irradiation;
参考文献
Kato,T. et al.
Chemical and Pharmaceutical Bulletin, 1979 , vol. 27, p. 1176 - 1180
反应条件
1: DBU / benzene / Heating 2: 70 percent / pyridinium tosylate / acetonitrile; H2O / 72 h / Ambient temperature View Scheme
参考文献
Antonioletti, Roberto; Bonadies, Francesco; Scettri, Arrigo
Gazzetta Chimica Italiana, 1991 , vol. 121, # 5 p. 233 - 234
反应条件
1: iodine, sodium carbonate / CH2Cl2 / Ambient temperature 2: DBU / benzene / Heating 3: 70 percent / pyridinium tosylate / acetonitrile; H2O / 72 h / Ambient temperature View Scheme
参考文献
Antonioletti, Roberto; Bonadies, Francesco; Scettri, Arrigo
Gazzetta Chimica Italiana, 1991 , vol. 121, # 5 p. 233 - 234
反应条件
in tetrahydrofuran Stirring (room temp., 15 h).; Extg. (ether), washing of ext. (aq. HCl, H2O), drying (Na2SO4), evapn. of solvent in vac., chromy. (hexane-ethyl acetate), elem. anal.;
参考文献
Itoh, Keiji; Nakanishi, Saburo; Otsuji, Yoshio
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 10 p. 2965 - 2977
参考文献
Ossipow; Korschun
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1903 , vol. 35, p. 630
Chem. Zentralbl., 1903 , vol. 74, # II p. 1281
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Weltner
Chemische Berichte, 1884 , vol. 17, p. 72
Chemische Berichte, 1885 , vol. 18, p. 790
