1: di-o-tolyl ethoxycarbonyl-methyl phosphate With sodium hydride in tetrahydrofuran
T=0°C;
2: benzaldehyde in tetrahydrofuran
T=-78°C; Horner-Wadsworth-Emmons olefination; 1.5 h; optical yield given as percent de;
参考文献
Pachali, Steffen; Hofmann, Christine; Rapp, Georg; Schobert, Rainer; Baro, Angelika; Frey, Wolfgang; Laschat, Sabine
European Journal of Organic Chemistry, 2009 , # 17 p. 2828 - 2835
1: With copper(l) iodide; trimethylsilyl trifluoromethanesulfonate; lithium chloride in tetrahydrofuran
T=-78°C; 1 h;
2: With trifluoroacetic acid in tetrahydrofuran
T=-78 - 20°C; Further stages.;
参考文献
Mueller, Amanda J.; Jennings, Michael P.
Organic Letters, 2007 , vol. 9, # 25 p. 5327 - 5329
