4-(9H-咔唑-9-基)苯硼酸合成路线 （共 8 条）
反应条件
1: With n-butyllithium in tetrahydrofuran T=-78°C; 3 h; Inert atmosphere; 2: With boric acid trimethyl ester in tetrahydrofuran T=-78°C; Inert atmosphere; 3: With hydrogenchloride in tetrahydrofuran; water T=-78 - 0°C; 3 h; Inert atmosphere;
参考文献
Wang, Kun-Yan; Chen, Chen; Liu, Jin-Fang; Wang, Qin; Chang, Jin; Zhu, Hong-Jun; Li, Chong
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 33 p. 6693 - 6704
反应条件
1: 9-(4-bromophenyl)carbazole With n-butyllithium in tetrahydrofuran; hexane T=-78 - -65°C; 1.5 h; Inert atmosphere; 2: boric acid trimethyl ester in tetrahydrofuran; hexane T=-65 - 20°C; Inert atmosphere;
参考文献
Guo, Lei; Li, King Fai; Wong, Man Shing; Cheah, Kok Wai
Chemical Communications, 2013 , vol. 49, # 34 p. 3597 - 3599
反应条件
1: 9-(4-bromophenyl)carbazole With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 3 h; Inert atmosphere; 2: boric acid trimethyl ester in tetrahydrofuran; hexane T=-78 - 20°C; 24 h; 3: hydrogenchloride
参考文献
Semiconductor Energy Laboratory Co., Ltd.
Patent: US8288012 B2, 2012 ;
Location in patent: Page/Page column 180-181 ;
反应条件
1.1: sodium t-butanolate / tris-(o-tolyl)phosphine; tris-(dibenzylideneacetone)dipalladium(0) / toluene / 6 h / 120 °C 2.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C 2.2: 24 h View Scheme
参考文献
Semiconductor Energy Laboratory Co., Ltd.
Patent: US8093399 B2, 2012 ;
反应条件
1.1: sodium t-butanolate / tris-(o-tolyl)phosphine; tris-(dibenzylideneacetone)dipalladium(0) / toluene / 6 h / 120 °C 2.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C 2.2: 24 h View Scheme
参考文献
Wang, Kun-Yan; Chen, Chen; Liu, Jin-Fang; Wang, Qin; Chang, Jin; Zhu, Hong-Jun; Li, Chong
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 33 p. 6693 - 6704
反应条件
1.1: copper(l) iodide; potassium carbonate / N,N-dimethyl-formamide / Reflux; Inert atmosphere 2.1: n-butyllithium / tetrahydrofuran / 3 h / -78 °C / Inert atmosphere 2.2: -78 °C / Inert atmosphere 2.3: 3 h / -78 - 0 °C / Inert atmosphere View Scheme
参考文献
Deng, Lijun; Wang, Xinzeng; Zhang, Zhengchuan; Li, Jiuyan
Journal of Materials Chemistry, 2012 , vol. 22, # 37 p. 19700 - 19708
反应条件
1: 9-(4-bromophenyl)carbazole With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane T=20°C; 12 h; Inert atmosphere;
参考文献
Park, Byung Sun; El-deeb, Ibrahim M.; Yoo, Kyung Ho; Han, Dong Keun; Tae, Jin Sung; Lee, So Ha
Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 11 p. 3629 - 3634
反应条件
palladium diacetate; potassium carbonate in ethanol; water
T=80°C; Suzuki Coupling; 0.666667 h;
参考文献
Rao, Xiaofeng; Liu, Chun; Qiu, Jieshan; Jin, Zilin
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 39 p. 7875 - 7883
